Crystal structure of dense metal-organic frameworks based on Sc(III) and two types of ligands

S. V. Cherezova; M. O. Barsukova; D. G. Samsonenko; V. P. Fedin

doi:10.1134/S0022476621060093

Crystal structure of dense metal-organic frameworks based on Sc(III) and two types of ligands

S. V. Cherezova, M. O. Barsukova, D. G. Samsonenko, V. P. Fedin

Факультет естественных наук

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc₂(HCOO)₂(OH)₂(bpydc)]·2H₂O (1) and [Sc(HCOO)(bdc)] (2), where bpydc^2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc^2– is terephthalate, HCOO^– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.

Язык оригинала	английский
Страницы (с-по)	897-904
Число страниц	8
Журнал	Journal of Structural Chemistry
Том	62
Номер выпуска	6
DOI	https://doi.org/10.1134/S0022476621060093
Состояние	Опубликовано - июн 2021

Предметные области OECD FOS+WOS

2.05 ТЕХНОЛОГИЯ МАТЕРИАЛОВ
1.04 ХИМИЧЕСКИЕ НАУКИ

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10.1134/S0022476621060093

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@article{97f5969f39c6425bbc554786d14d86f7,

title = "Crystal structure of dense metal-organic frameworks based on Sc(III) and two types of ligands",

abstract = "Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.",

keywords = "2,2′-bipyridine-4,4′-dicarboxylic acid, metal-organic frameworks, scandium, terephthalic acid, XRD",

author = "Cherezova, {S. V.} and Barsukova, {M. O.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

note = "Funding Information: The study was supported by the Russian Science Foundation (project No.19-73-00169). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = jun,

doi = "10.1134/S0022476621060093",

language = "English",

volume = "62",

pages = "897--904",

journal = "Journal of Structural Chemistry",

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number = "6",

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Crystal structure of dense metal-organic frameworks based on Sc(III) and two types of ligands. / Cherezova, S. V.; Barsukova, M. O.; Samsonenko, D. G.; Fedin, V. P.

В: Journal of Structural Chemistry, Том 62, № 6, 06.2021, стр. 897-904.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal structure of dense metal-organic frameworks based on Sc(III) and two types of ligands

AU - Cherezova, S. V.

AU - Barsukova, M. O.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

PY - 2021/6

Y1 - 2021/6

N2 - Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.

AB - Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.

KW - 2,2′-bipyridine-4,4′-dicarboxylic acid

KW - metal-organic frameworks

KW - scandium

KW - terephthalic acid

KW - XRD

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DO - 10.1134/S0022476621060093

M3 - Article

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JO - Journal of Structural Chemistry

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