Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex

A. A. Sapianik; E. E. Semenenko; D. G. Samsonenko; D. N. Dybtsev; V. P. Fedin

doi:10.1134/S0022476618020336

Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex

A. A. Sapianik, E. E. Semenenko, D. G. Samsonenko, D. N. Dybtsev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

7 Цитирования (Scopus)

Аннотация

Three new metal-organic frameworks [Zn(Hibdc)₂]·DMF (1), (H₂NMe₂)[Li₂Zn₃(H₂O)(dmf)(Hbtc)₃(btc)]·6DMF·H₂O (2), and [Li₂Zn₂(H₂O)₂(bpp)(bpdc)₃]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li₂Zn₂(piv)₆(py)₂] with isophthalic (H₂ibdc) and trimesic (H₃btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H₂bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li₂Zn₂} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.

Язык оригинала	английский
Страницы (с-по)	487-493
Число страниц	7
Журнал	Journal of Structural Chemistry
Том	59
Номер выпуска	2
DOI	https://doi.org/10.1134/S0022476618020336
Состояние	Опубликовано - 1 мар 2018

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10.1134/S0022476618020336

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title = "Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex",

abstract = "Three new metal-organic frameworks [Zn(Hibdc)2]·DMF (1), (H2NMe2)[Li2Zn3(H2O)(dmf)(Hbtc)3(btc)]·6DMF·H2O (2), and [Li2Zn2(H2O)2(bpp)(bpdc)3]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)6(py)2] with isophthalic (H2ibdc) and trimesic (H3btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H2bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.",

keywords = "carboxylate complexes, coordination polymers, lithium, metal-organic frameworks, polynuclear complexes, single crystal X-ray diffraction analysis, zinc, METAL-ORGANIC FRAMEWORKS",

author = "Sapianik, {A. A.} and Semenenko, {E. E.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

year = "2018",

month = mar,

day = "1",

doi = "10.1134/S0022476618020336",

language = "English",

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Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex. / Sapianik, A. A.; Semenenko, E. E.; Samsonenko, D. G.; Dybtsev, D. N.; Fedin, V. P.

В: Journal of Structural Chemistry, Том 59, № 2, 01.03.2018, стр. 487-493.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex

AU - Sapianik, A. A.

AU - Semenenko, E. E.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - Three new metal-organic frameworks [Zn(Hibdc)2]·DMF (1), (H2NMe2)[Li2Zn3(H2O)(dmf)(Hbtc)3(btc)]·6DMF·H2O (2), and [Li2Zn2(H2O)2(bpp)(bpdc)3]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)6(py)2] with isophthalic (H2ibdc) and trimesic (H3btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H2bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.

AB - Three new metal-organic frameworks [Zn(Hibdc)2]·DMF (1), (H2NMe2)[Li2Zn3(H2O)(dmf)(Hbtc)3(btc)]·6DMF·H2O (2), and [Li2Zn2(H2O)2(bpp)(bpdc)3]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)6(py)2] with isophthalic (H2ibdc) and trimesic (H3btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H2bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.

KW - carboxylate complexes

KW - coordination polymers

KW - lithium

KW - metal-organic frameworks

KW - polynuclear complexes

KW - single crystal X-ray diffraction analysis

KW - zinc

KW - METAL-ORGANIC FRAMEWORKS

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JO - Journal of Structural Chemistry

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