Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O

A. V. Anyushin; A. I. Smolentsev; M. N. Sokolov

doi:10.1134/S0022476617030222

Crystal structure of a new magnesium paratungstate salt (CH₃NH₃)₄[(Mg(H₂O)₅)₂H₆W₁₂O₄₂]Br₂·8H₂O

A. V. Anyushin, A. I. Smolentsev, M. N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

The X-ray crystal structure of (CH₃NH₃)₄[(Mg(H₂O)₅)₂(H₆W₁₂O₄₂)]Br₂·8H₂O (1) obtained by a reaction of Li₂WO₄·H₂O and Mg(NO₃)₂·6H₂O in the presence of MeNH₃Br is reported. Crystallographic parameters are: triclinic, space group P-1, a = 10.8280(4) Å, b = 12.4866(5) Å, c = 12.6201(5) Å, α = 108.501(1)°, β = 111.542(1)°, γ = 91.139(1)°, V = 1486.98(10) Å³, Z = 1, C₄H₆₆Br₂Mg₂N₄O₆₀W₁₂, d_x = 3.959 g/cm³, T = 150 K, R₁ = 0.030 for 9914 F_o > 4δ(F) until 2θ_max = 66.6° The structure contains tetraprotonated [H₂W₁₂O₄₂]^10– anions coordinated with {Mg(H₂O)₅}²⁺ cations as ditopic ligands via terminal oxygen atoms. The crystal structure also incorporates outer-sphere CH₃NH₃ ⁺ and Br^– ions. The Mg²⁺ cations are in the octahedral environment, Mg–O(H₂O) and Mg–O(W) bond lengths being 2.102(5)÷2.044(5) Å and 2.071(5) Å, respectively.

Язык оригинала	английский
Страницы (с-по)	597-599
Число страниц	3
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	3
DOI	https://doi.org/10.1134/S0022476617030222
Состояние	Опубликовано - 1 мая 2017

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10.1134/S0022476617030222

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@article{ce81e2fce8d7467b9300720ebfe15458,

title = "Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O",

abstract = "The X-ray crystal structure of (CH3NH3)4[(Mg(H2O)5)2(H6W12O42)]Br2·8H2O (1) obtained by a reaction of Li2WO4·H2O and Mg(NO3)2·6H2O in the presence of MeNH3Br is reported. Crystallographic parameters are: triclinic, space group P-1, a = 10.8280(4) {\AA}, b = 12.4866(5) {\AA}, c = 12.6201(5) {\AA}, α = 108.501(1)°, β = 111.542(1)°, γ = 91.139(1)°, V = 1486.98(10) {\AA}3, Z = 1, C4H66Br2Mg2N4O60W12, dx = 3.959 g/cm3, T = 150 K, R1 = 0.030 for 9914 Fo > 4δ(F) until 2θmax = 66.6° The structure contains tetraprotonated [H2W12O42]10– anions coordinated with {Mg(H2O)5}2+ cations as ditopic ligands via terminal oxygen atoms. The crystal structure also incorporates outer-sphere CH3NH3 + and Br– ions. The Mg2+ cations are in the octahedral environment, Mg–O(H2O) and Mg–O(W) bond lengths being 2.102(5)÷2.044(5) {\AA} and 2.071(5) {\AA}, respectively.",

keywords = "crystal structure, magnesium, paratungstate B, polyoxometalates, CLUSTERS, COMPLEXES, IONS, PARADODECATUNGSTATE",

author = "Anyushin, {A. V.} and Smolentsev, {A. I.} and Sokolov, {M. N.}",

year = "2017",

month = may,

day = "1",

doi = "10.1134/S0022476617030222",

language = "English",

volume = "58",

pages = "597--599",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "3",

}

Crystal structure of a new magnesium paratungstate salt (CH₃NH₃)₄[(Mg(H₂O)₅)₂H₆W₁₂O₄₂]Br₂·8H₂O. / Anyushin, A. V.; Smolentsev, A. I.; Sokolov, M. N.

В: Journal of Structural Chemistry, Том 58, № 3, 01.05.2017, стр. 597-599.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O

AU - Anyushin, A. V.

AU - Smolentsev, A. I.

AU - Sokolov, M. N.

PY - 2017/5/1

Y1 - 2017/5/1

N2 - The X-ray crystal structure of (CH3NH3)4[(Mg(H2O)5)2(H6W12O42)]Br2·8H2O (1) obtained by a reaction of Li2WO4·H2O and Mg(NO3)2·6H2O in the presence of MeNH3Br is reported. Crystallographic parameters are: triclinic, space group P-1, a = 10.8280(4) Å, b = 12.4866(5) Å, c = 12.6201(5) Å, α = 108.501(1)°, β = 111.542(1)°, γ = 91.139(1)°, V = 1486.98(10) Å3, Z = 1, C4H66Br2Mg2N4O60W12, dx = 3.959 g/cm3, T = 150 K, R1 = 0.030 for 9914 Fo > 4δ(F) until 2θmax = 66.6° The structure contains tetraprotonated [H2W12O42]10– anions coordinated with {Mg(H2O)5}2+ cations as ditopic ligands via terminal oxygen atoms. The crystal structure also incorporates outer-sphere CH3NH3 + and Br– ions. The Mg2+ cations are in the octahedral environment, Mg–O(H2O) and Mg–O(W) bond lengths being 2.102(5)÷2.044(5) Å and 2.071(5) Å, respectively.

AB - The X-ray crystal structure of (CH3NH3)4[(Mg(H2O)5)2(H6W12O42)]Br2·8H2O (1) obtained by a reaction of Li2WO4·H2O and Mg(NO3)2·6H2O in the presence of MeNH3Br is reported. Crystallographic parameters are: triclinic, space group P-1, a = 10.8280(4) Å, b = 12.4866(5) Å, c = 12.6201(5) Å, α = 108.501(1)°, β = 111.542(1)°, γ = 91.139(1)°, V = 1486.98(10) Å3, Z = 1, C4H66Br2Mg2N4O60W12, dx = 3.959 g/cm3, T = 150 K, R1 = 0.030 for 9914 Fo > 4δ(F) until 2θmax = 66.6° The structure contains tetraprotonated [H2W12O42]10– anions coordinated with {Mg(H2O)5}2+ cations as ditopic ligands via terminal oxygen atoms. The crystal structure also incorporates outer-sphere CH3NH3 + and Br– ions. The Mg2+ cations are in the octahedral environment, Mg–O(H2O) and Mg–O(W) bond lengths being 2.102(5)÷2.044(5) Å and 2.071(5) Å, respectively.

KW - crystal structure

KW - magnesium

KW - paratungstate B

KW - polyoxometalates

KW - CLUSTERS

KW - COMPLEXES

KW - IONS

KW - PARADODECATUNGSTATE

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U2 - 10.1134/S0022476617030222

DO - 10.1134/S0022476617030222

M3 - Article

AN - SCOPUS:85021202085

VL - 58

SP - 597

EP - 599

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -