Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex

A. A. Ivanov; N. V. Kuratieva; M. A. Shestopalov; Yu V. Mironov

doi:10.1134/S0022476617050195

Crystal structure of a [CsK₂(μ₃-DMF)₂(μ-DMF)₃(DMF)₄][{Re₆(μ³-Se)₈}Br₆] cluster complex

A. A. Ivanov, N. V. Kuratieva, M. A. Shestopalov, Yu V. Mironov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

A cluster complex of the composition [CsK₂(μ₃-DMF)₂(μ-DMF)₃(DMF)₄][{Re₆(μ₃-Se)₈}Br₆] is obtained by the reaction of K₄[{Re₆(μ₃-Se)₈}(OH)₆]·8H₂O with hydrobromic acid in the presence of CsBr and its subsequent crystallization by diethyl ether diffusion in a dimethylformamide solution. The compound crystallizes in the triclinic space group P1̅, with the following unit cell parameters: a = 13.6169(3) Å, b = 14.7584(4) Å, c = 18.1573(4) Å, α = 103.332(1)°, β = 108.250(1)°, γ = 97.371(1)°, V = 3286.55(14) Å³, Z = 2, d_calc = 3.130 g/cm³. The crystal structure is built of [{Re₆Se₈}Br₆]^3– anionic cluster complexes and complex [CsK₂(μ₃-DMF)₂(μ-DMF)₃(DMF)₄]³⁺ cations.

Язык оригинала	английский
Страницы (с-по)	989-993
Число страниц	5
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	5
DOI	https://doi.org/10.1134/S0022476617050195
Состояние	Опубликовано - 1 сент. 2017

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@article{f81e78feb5c74ed58c8836026f94d59a,

title = "Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex",

abstract = "A cluster complex of the composition [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] is obtained by the reaction of K4[{Re6(μ3-Se)8}(OH)6]·8H2O with hydrobromic acid in the presence of CsBr and its subsequent crystallization by diethyl ether diffusion in a dimethylformamide solution. The compound crystallizes in the triclinic space group P1̅, with the following unit cell parameters: a = 13.6169(3) {\AA}, b = 14.7584(4) {\AA}, c = 18.1573(4) {\AA}, α = 103.332(1)°, β = 108.250(1)°, γ = 97.371(1)°, V = 3286.55(14) {\AA}3, Z = 2, dcalc = 3.130 g/cm3. The crystal structure is built of [{Re6Se8}Br6]3– anionic cluster complexes and complex [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4]3+ cations.",

keywords = "crystal structure, octahedral chalcogenide clusters, rhenium, CORE, ORGANIC-LIGANDS, ENCAPSULATION, LUMINESCENCE PROPERTIES, RHENIUM, CHALCOGENIDE CLUSTERS, SE, OCTAHEDRAL CLUSTERS, SILICA NANOPARTICLES, CHEMISTRY",

author = "Ivanov, {A. A.} and Kuratieva, {N. V.} and Shestopalov, {M. A.} and Mironov, {Yu V.}",

year = "2017",

month = sep,

day = "1",

doi = "10.1134/S0022476617050195",

language = "English",

volume = "58",

pages = "989--993",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "5",

}

Crystal structure of a [CsK₂(μ₃-DMF)₂(μ-DMF)₃(DMF)₄][{Re₆(μ³-Se)₈}Br₆] cluster complex. / Ivanov, A. A.; Kuratieva, N. V.; Shestopalov, M. A. и др.

В: Journal of Structural Chemistry, Том 58, № 5, 01.09.2017, стр. 989-993.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal structure of a [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] cluster complex

AU - Ivanov, A. A.

AU - Kuratieva, N. V.

AU - Shestopalov, M. A.

AU - Mironov, Yu V.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - A cluster complex of the composition [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] is obtained by the reaction of K4[{Re6(μ3-Se)8}(OH)6]·8H2O with hydrobromic acid in the presence of CsBr and its subsequent crystallization by diethyl ether diffusion in a dimethylformamide solution. The compound crystallizes in the triclinic space group P1̅, with the following unit cell parameters: a = 13.6169(3) Å, b = 14.7584(4) Å, c = 18.1573(4) Å, α = 103.332(1)°, β = 108.250(1)°, γ = 97.371(1)°, V = 3286.55(14) Å3, Z = 2, dcalc = 3.130 g/cm3. The crystal structure is built of [{Re6Se8}Br6]3– anionic cluster complexes and complex [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4]3+ cations.

AB - A cluster complex of the composition [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4][{Re6(μ3-Se)8}Br6] is obtained by the reaction of K4[{Re6(μ3-Se)8}(OH)6]·8H2O with hydrobromic acid in the presence of CsBr and its subsequent crystallization by diethyl ether diffusion in a dimethylformamide solution. The compound crystallizes in the triclinic space group P1̅, with the following unit cell parameters: a = 13.6169(3) Å, b = 14.7584(4) Å, c = 18.1573(4) Å, α = 103.332(1)°, β = 108.250(1)°, γ = 97.371(1)°, V = 3286.55(14) Å3, Z = 2, dcalc = 3.130 g/cm3. The crystal structure is built of [{Re6Se8}Br6]3– anionic cluster complexes and complex [CsK2(μ3-DMF)2(μ-DMF)3(DMF)4]3+ cations.

KW - crystal structure

KW - octahedral chalcogenide clusters

KW - rhenium

KW - CORE

KW - ORGANIC-LIGANDS

KW - ENCAPSULATION

KW - LUMINESCENCE PROPERTIES

KW - RHENIUM

KW - CHALCOGENIDE CLUSTERS

KW - SE

KW - OCTAHEDRAL CLUSTERS

KW - SILICA NANOPARTICLES

KW - CHEMISTRY

UR - http://www.scopus.com/inward/record.url?scp=85032288600&partnerID=8YFLogxK

U2 - 10.1134/S0022476617050195

DO - 10.1134/S0022476617050195

M3 - Article

AN - SCOPUS:85032288600

VL - 58

SP - 989

EP - 993

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -