Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O

Ilia V. Kochetygov; Evgeny Yu Filatov; Natalia V. Kuratieva; Pavel E. Plyusnin; Dmitry Yu Naumov; Andrey V. Zadesenets; Sergey V. Korenev; Alphiya R. Tsygankova; Vladimir A. Logvinenko

doi:10.1007/s10973-016-5687-0

Crystal structure and thermal properties of K₃[Ir(C₂O₄)₃]·4.25H₂O and K₃[Ir(C₂O₄)₃]·0.5KCl·4H₂O

Ilia V. Kochetygov, Evgeny Yu Filatov, Natalia V. Kuratieva, Pavel E. Plyusnin, Dmitry Yu Naumov, Andrey V. Zadesenets, Sergey V. Korenev, Alphiya R. Tsygankova, Vladimir A. Logvinenko

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

The structures of K₃[Ir(C₂O₄)₃]·0.5KCl·4H₂O and K₃[Ir(C₂O₄)₃]·4.25H₂O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO₂ was shown. It is found that the redox process with CO₂ release passes easier for K₃[Ir(C₂O₄)₃]·0.5KCl compound than for K₃[Ir(C₂O₄)₃] one.

Язык оригинала	английский
Страницы (с-по)	1541-1548
Число страниц	8
Журнал	Journal of Thermal Analysis and Calorimetry
Том	126
Номер выпуска	3
DOI	https://doi.org/10.1007/s10973-016-5687-0
Состояние	Опубликовано - 1 дек. 2016

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10.1007/s10973-016-5687-0

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Подробные сведения о темах исследования «Crystal structure and thermal properties of K₃[Ir(C₂O₄)₃]·4.25H₂O and K₃[Ir(C₂O₄)₃]·0.5KCl·4H₂O». Вместе они формируют уникальный семантический отпечаток (fingerprint).

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Kochetygov, I. V., Filatov, E. Y., Kuratieva, N. V., Plyusnin, P. E., Naumov, D. Y., Zadesenets, A. V., Korenev, S. V., Tsygankova, A. R., & Logvinenko, V. A. (2016). Crystal structure and thermal properties of K₃[Ir(C₂O₄)₃]·4.25H₂O and K₃[Ir(C₂O₄)₃]·0.5KCl·4H₂O. Journal of Thermal Analysis and Calorimetry, 126(3), 1541-1548. https://doi.org/10.1007/s10973-016-5687-0

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title = "Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O",

abstract = "The structures of K3[Ir(C2O4)3]·0.5KCl·4H2O and K3[Ir(C2O4)3]·4.25H2O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO2 was shown. It is found that the redox process with CO2 release passes easier for K3[Ir(C2O4)3]·0.5KCl compound than for K3[Ir(C2O4)3] one.",

keywords = "Crystal structure, Iridium, Oxalatocomplexes, Thermal decomposition",

author = "Kochetygov, {Ilia V.} and Filatov, {Evgeny Yu} and Kuratieva, {Natalia V.} and Plyusnin, {Pavel E.} and Naumov, {Dmitry Yu} and Zadesenets, {Andrey V.} and Korenev, {Sergey V.} and Tsygankova, {Alphiya R.} and Logvinenko, {Vladimir A.}",

year = "2016",

month = dec,

day = "1",

doi = "10.1007/s10973-016-5687-0",

language = "English",

volume = "126",

pages = "1541--1548",

journal = "Journal of Thermal Analysis and Calorimetry",

issn = "1388-6150",

publisher = "Springer Nature",

number = "3",

}

Crystal structure and thermal properties of K₃[Ir(C₂O₄)₃]·4.25H₂O and K₃[Ir(C₂O₄)₃]·0.5KCl·4H₂O. / Kochetygov, Ilia V.; Filatov, Evgeny Yu ; Kuratieva, Natalia V. и др.

В: Journal of Thermal Analysis and Calorimetry, Том 126, № 3, 01.12.2016, стр. 1541-1548.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O

AU - Kochetygov, Ilia V.

AU - Filatov, Evgeny Yu

AU - Kuratieva, Natalia V.

AU - Plyusnin, Pavel E.

AU - Naumov, Dmitry Yu

AU - Zadesenets, Andrey V.

AU - Korenev, Sergey V.

AU - Tsygankova, Alphiya R.

AU - Logvinenko, Vladimir A.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - The structures of K3[Ir(C2O4)3]·0.5KCl·4H2O and K3[Ir(C2O4)3]·4.25H2O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO2 was shown. It is found that the redox process with CO2 release passes easier for K3[Ir(C2O4)3]·0.5KCl compound than for K3[Ir(C2O4)3] one.

AB - The structures of K3[Ir(C2O4)3]·0.5KCl·4H2O and K3[Ir(C2O4)3]·4.25H2O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO2 was shown. It is found that the redox process with CO2 release passes easier for K3[Ir(C2O4)3]·0.5KCl compound than for K3[Ir(C2O4)3] one.

KW - Crystal structure

KW - Iridium

KW - Oxalatocomplexes

KW - Thermal decomposition

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U2 - 10.1007/s10973-016-5687-0

DO - 10.1007/s10973-016-5687-0

M3 - Article

AN - SCOPUS:84978096879

VL - 126

SP - 1541

EP - 1548

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

SN - 1388-6150

IS - 3

ER -