Аннотация
The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S5 2–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.
Язык оригинала | английский |
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Страницы (с-по) | 964-969 |
Число страниц | 6 |
Журнал | Journal of Structural Chemistry |
Том | 58 |
Номер выпуска | 5 |
DOI | |
Состояние | Опубликовано - 1 сен 2017 |