Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]

A. A. Sapianik; E. R. Dudko; D. G. Samsonenko; V. P. Fedin

doi:10.1134/S0022476620120148

Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li₂Zn₂(py)₂(piv)₆]

A. A. Sapianik, E. R. Dudko, D. G. Samsonenko, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

In the interaction of the heterometallic complex [Li₂Zn₂(py)₂(piv)₆] (piv^– is the pivalate anion, py is pyridine) with 2,5-dibromoterephthalic acid (H₂Br₂-bdc) or 9,10-anthracenedicarboxylic acid (H₂adc), two coordination polymers [Li(DMF)(HBr₂-bdc)] (1) and (Me₂NH₂)[Zn(Hadc) (adc)]·DMF·H₂O (2) are obtained. During the synthesis, the initial tetranuclear heterometallic fragment is completely fragmentated. When the same complex interacts with nitroterephthalic acid (H₂NO₂-bdc), a heterometallic metal-organic framework (Me₂NH₂)[LiZn(NO₂- bdc)₂]·DMF (3) is formed. Resulting coordination polymer 3 has a three-dimensional porous structure; binuclear heterometallic carboxylate moieties {LiZn(COO)₃} act as secondary building blocks.

Язык оригинала	английский
Страницы (с-по)	1957-1964
Число страниц	8
Журнал	Journal of Structural Chemistry
Том	61
Номер выпуска	12
DOI	https://doi.org/10.1134/S0022476620120148
Состояние	Опубликовано - дек. 2020

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title = "Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]",

abstract = "In the interaction of the heterometallic complex [Li2Zn2(py)2(piv)6] (piv– is the pivalate anion, py is pyridine) with 2,5-dibromoterephthalic acid (H2Br2-bdc) or 9,10-anthracenedicarboxylic acid (H2adc), two coordination polymers [Li(DMF)(HBr2-bdc)] (1) and (Me2NH2)[Zn(Hadc) (adc)]·DMF·H2O (2) are obtained. During the synthesis, the initial tetranuclear heterometallic fragment is completely fragmentated. When the same complex interacts with nitroterephthalic acid (H2NO2-bdc), a heterometallic metal-organic framework (Me2NH2)[LiZn(NO2- bdc)2]·DMF (3) is formed. Resulting coordination polymer 3 has a three-dimensional porous structure; binuclear heterometallic carboxylate moieties {LiZn(COO)3} act as secondary building blocks.",

keywords = "coordination polymers, heterometallic complexes, lithium, polycarboxylic acids, X-ray diffraction analysis, zinc, DESIGN, INFINITE POLYMERIC FRAMEWORKS",

author = "Sapianik, {A. A.} and Dudko, {E. R.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

note = "Funding Information: The study was supported by the Russian Science Foundation (project No. 19-73-00171). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = dec,

doi = "10.1134/S0022476620120148",

language = "English",

volume = "61",

pages = "1957--1964",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "12",

}

Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li₂Zn₂(py)₂(piv)₆]. / Sapianik, A. A.; Dudko, E. R.; Samsonenko, D. G. и др.

В: Journal of Structural Chemistry, Том 61, № 12, 12.2020, стр. 1957-1964.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]

AU - Sapianik, A. A.

AU - Dudko, E. R.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

N1 - Funding Information: The study was supported by the Russian Science Foundation (project No. 19-73-00171). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - In the interaction of the heterometallic complex [Li2Zn2(py)2(piv)6] (piv– is the pivalate anion, py is pyridine) with 2,5-dibromoterephthalic acid (H2Br2-bdc) or 9,10-anthracenedicarboxylic acid (H2adc), two coordination polymers [Li(DMF)(HBr2-bdc)] (1) and (Me2NH2)[Zn(Hadc) (adc)]·DMF·H2O (2) are obtained. During the synthesis, the initial tetranuclear heterometallic fragment is completely fragmentated. When the same complex interacts with nitroterephthalic acid (H2NO2-bdc), a heterometallic metal-organic framework (Me2NH2)[LiZn(NO2- bdc)2]·DMF (3) is formed. Resulting coordination polymer 3 has a three-dimensional porous structure; binuclear heterometallic carboxylate moieties {LiZn(COO)3} act as secondary building blocks.

AB - In the interaction of the heterometallic complex [Li2Zn2(py)2(piv)6] (piv– is the pivalate anion, py is pyridine) with 2,5-dibromoterephthalic acid (H2Br2-bdc) or 9,10-anthracenedicarboxylic acid (H2adc), two coordination polymers [Li(DMF)(HBr2-bdc)] (1) and (Me2NH2)[Zn(Hadc) (adc)]·DMF·H2O (2) are obtained. During the synthesis, the initial tetranuclear heterometallic fragment is completely fragmentated. When the same complex interacts with nitroterephthalic acid (H2NO2-bdc), a heterometallic metal-organic framework (Me2NH2)[LiZn(NO2- bdc)2]·DMF (3) is formed. Resulting coordination polymer 3 has a three-dimensional porous structure; binuclear heterometallic carboxylate moieties {LiZn(COO)3} act as secondary building blocks.

KW - coordination polymers

KW - heterometallic complexes

KW - lithium

KW - polycarboxylic acids

KW - X-ray diffraction analysis

KW - zinc

KW - DESIGN

KW - INFINITE POLYMERIC FRAMEWORKS

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U2 - 10.1134/S0022476620120148

DO - 10.1134/S0022476620120148

M3 - Article

AN - SCOPUS:85098050992

VL - 61

SP - 1957

EP - 1964

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

ER -