Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand

M. O. Barsukova, D. G. Samsonenko, T. V. Goncharova, A. S. Potapov, S. A. Sapchenko, D. N. Dybtsev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданияхстатья

6 Цитирования (Scopus)

Аннотация

1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

Язык оригиналаанглийский
Страницы (с-по)2914-2919
Число страниц6
ЖурналRussian Chemical Bulletin
Том65
Номер выпуска12
DOI
СостояниеОпубликовано - 1 дек 2016

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