Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand

M. O. Barsukova; D. G. Samsonenko; T. V. Goncharova; A. S. Potapov; S. A. Sapchenko; D. N. Dybtsev; V. P. Fedin

doi:10.1007/s11172-016-1677-4

Coordination polymers with adjustable dimensionality based on Cu^II and bis-imidazolyl bridging ligand

M. O. Barsukova, D. G. Samsonenko, T. V. Goncharova, A. S. Potapov, S. A. Sapchenko, D. N. Dybtsev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

6 Цитирования (Scopus)

Аннотация

1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl₂] (1) and [Cu(bImB)₂Cl₂] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

Язык оригинала	английский
Страницы (с-по)	2914-2919
Число страниц	6
Журнал	Russian Chemical Bulletin
Том	65
Номер выпуска	12
DOI	https://doi.org/10.1007/s11172-016-1677-4
Состояние	Опубликовано - 1 дек. 2016

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10.1007/s11172-016-1677-4

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title = "Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand",

abstract = "1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.",

keywords = "bis(imidazolyl)alkanes, coordination polymer, copper, X-ray diffraction",

author = "Barsukova, {M. O.} and Samsonenko, {D. G.} and Goncharova, {T. V.} and Potapov, {A. S.} and Sapchenko, {S. A.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

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Coordination polymers with adjustable dimensionality based on Cu^II and bis-imidazolyl bridging ligand. / Barsukova, M. O.; Samsonenko, D. G.; Goncharova, T. V. и др.

В: Russian Chemical Bulletin, Том 65, № 12, 01.12.2016, стр. 2914-2919.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand

AU - Barsukova, M. O.

AU - Samsonenko, D. G.

AU - Goncharova, T. V.

AU - Potapov, A. S.

AU - Sapchenko, S. A.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - 1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

AB - 1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

KW - bis(imidazolyl)alkanes

KW - coordination polymer

KW - copper

KW - X-ray diffraction

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DO - 10.1007/s11172-016-1677-4

M3 - Article

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