Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid

A. A. Lysova; V. A. Dubskikh; K. D. Abasheeva; A. A. Vasileva; D. G. Samsonenko; D. N. Dybtsev

doi:10.1134/S1070328421090062

Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid

A. A. Lysova, V. A. Dubskikh, K. D. Abasheeva, A. A. Vasileva, D. G. Samsonenko, D. N. Dybtsev

Факультет естественных наук

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H₂Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me₂NH₂)[Sc₃(Tdc)₄(OH)₂]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.

Язык оригинала	английский
Страницы (с-по)	593-600
Число страниц	8
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	47
Номер выпуска	9
DOI	https://doi.org/10.1134/S1070328421090062
Состояние	Опубликовано - сен 2021

Предметные области OECD FOS+WOS

2.04 ХИМИЧЕСКИЕ ТЕХНОЛОГИИ
1.04 ХИМИЧЕСКИЕ НАУКИ

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10.1134/S1070328421090062

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title = "Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid",

abstract = "Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H2Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me2NH2)[Sc3(Tdc)4(OH)2]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.",

keywords = "2,5-thiophenedicarboxylic acid, metal−organic frameworks, scandium(III)",

author = "Lysova, {A. A.} and Dubskikh, {V. A.} and Abasheeva, {K. D.} and Vasileva, {A. A.} and Samsonenko, {D. G.} and Dybtsev, {D. N.}",

note = "Funding Information: This work was supported by the Russian Foundation for Basic Research and Government of the Novosibirsk oblast, project no. 20-43-540010. Publisher Copyright: {\textcopyright} 2021, The Author(s).",

year = "2021",

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doi = "10.1134/S1070328421090062",

language = "English",

volume = "47",

pages = "593--600",

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Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid. / Lysova, A. A.; Dubskikh, V. A.; Abasheeva, K. D.; Vasileva, A. A.; Samsonenko, D. G.; Dybtsev, D. N.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 47, № 9, 09.2021, стр. 593-600.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid

AU - Lysova, A. A.

AU - Dubskikh, V. A.

AU - Abasheeva, K. D.

AU - Vasileva, A. A.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research and Government of the Novosibirsk oblast, project no. 20-43-540010. Publisher Copyright: © 2021, The Author(s).

PY - 2021/9

Y1 - 2021/9

N2 - Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H2Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me2NH2)[Sc3(Tdc)4(OH)2]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.

AB - Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H2Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me2NH2)[Sc3(Tdc)4(OH)2]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.

KW - 2,5-thiophenedicarboxylic acid

KW - metal−organic frameworks

KW - scandium(III)

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M3 - Article

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VL - 47

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JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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SN - 1070-3284

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Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid

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