Coordination Polymers of Cadmium with Di(pyrazol-1-yl)alkane-4,4'-dicarboxylic Acids: Synthesis, Crystal Structures, and Luminescence Properties

E. A. Pershina; N. P. Burlutskiy; D. I. Pavlov; A. A. Ryadun; V. P. Fedin; A. S. Potapov

doi:10.1134/S1070328422100049

Coordination Polymers of Cadmium with Di(pyrazol-1-yl)alkane-4,4'-dicarboxylic Acids: Synthesis, Crystal Structures, and Luminescence Properties

Переведенное название: Синтез, кристаллическая структура и люминесцентные свойства координационных полимеров кадмия с ди(пиразол-1-ил)алкан-4,4'-дикарбоновыми кислотами

E. A. Pershina, N. P. Burlutskiy, D. I. Pavlov, A. A. Ryadun, V. P. Fedin, A. S. Potapov

Факультет естественных наук

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Синтезированы координационные полимеры кадмия(II) с производными ди(пиразол-1-ил)алканов – бис(3,5-диметилпиразол-1-ил)метан-4,4′-дикарбоновой кислотой (H2L1) и 1,3-бис(пиразол-1-ил)пропан-4,4′-дикарбоновой кислотой (H2L2). Кристаллическая структура продуктов была установлена методом рентгеноструктурного анализа (CCDC № 2172853 (I), 2172854 (II)). Ионы Cd2+ и дикарбоновая кислота с одной метиленовой группой между пиразольными циклами образуют трехмерный координационный полимер с однократным взаимопрорастанием координационных сеток, тогда как в случае трех метиленовых групп образуется двухмерный координационный полимер, слои которого связаны водородными связями с участием молекул воды в координационной сфере ионов Cd2+. В спектрах люминесценции полученных координационных полимеров наблюдалось две полосы – с локальным внутрилигандным возбуждением и переносом заряда металл-лиганд.

Переведенное название	Синтез, кристаллическая структура и люминесцентные свойства координационных полимеров кадмия с ди(пиразол-1-ил)алкан-4,4'-дикарбоновыми кислотами
Язык оригинала	английский
Страницы (с-по)	601-607
Число страниц	7
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	48
Номер выпуска	10
DOI	https://doi.org/10.1134/S1070328422100049
Состояние	Опубликовано - окт. 2022

Предметные области OECD FOS+WOS

2.04 ХИМИЧЕСКИЕ ТЕХНОЛОГИИ
1.04 ХИМИЧЕСКИЕ НАУКИ

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10.1134/S1070328422100049

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Pershina, E. A., Burlutskiy, N. P., Pavlov, D. I., Ryadun, A. A., Fedin, V. P., & Potapov, A. S. (2022). Coordination Polymers of Cadmium with Di(pyrazol-1-yl)alkane-4,4'-dicarboxylic Acids: Synthesis, Crystal Structures, and Luminescence Properties. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 48(10), 601-607. https://doi.org/10.1134/S1070328422100049

@article{c3f89af4e4db45f5b34e0b2bb6843d36,

title = "Coordination Polymers of Cadmium with Di(pyrazol-1-yl)alkane-4,4'-dicarboxylic Acids: Synthesis, Crystal Structures, and Luminescence Properties",

abstract = "Coordination polymers of cadmium(II) with the di(pyrazol-1-yl)alkane derivatives, bis(3,5-dimethylpyrazol-1-yl)methane-4,4′-dicarboxylic acid (H2L1) and 1,3-bis(pyrazol-1-yl)propane-4,4′-dicarboxylic acid (H2L2), are synthesized. The crystal structures of the products are determined by X-ray diffraction (CIF files CCDC nos. 2172853 (I) and 2172854 (II)). The Cd2+ ions and dicarboxylic acid with one methylene group between the pyrazole cycles form a three-dimensional coordination polymer with a single mutual intergrowing of coordination networks, whereas three methylene groups result in the formation of a two-dimensional coordination polymer, the layers of which are linked by hydrogen bonds involving water molecules in the coordination sphere of the Cd2+ ions. The luminescence spectra of the synthesized coordination polymers exhibit two bands: with the local intraligand excitation and with the metal–ligand charge transfer.",

keywords = "cadmium, coordination polymers, dicarboxylic acids, luminescence, pyrazole",

author = "Pershina, {E. A.} and Burlutskiy, {N. P.} and Pavlov, {D. I.} and Ryadun, {A. A.} and Fedin, {V. P.} and Potapov, {A. S.}",

note = "Funding Information: This work was supported by the Committee of Science of the Ministry of Education and Science of Kazakhstan (grant no. AP08856049). The physicochemical characterization of the synthesized compounds was carried out at the Center for Collective Use at the Nikolaev Institute of Inorganic Chemistry (Siberian Branch, Russian Academy of Sciences) and supported by the Ministry of Science and Higher Education of the Russian Federation (projects nos. 121031700321-3 and 121031700313-8). Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",

year = "2022",

month = oct,

doi = "10.1134/S1070328422100049",

language = "English",

volume = "48",

pages = "601--607",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "10",

}

Pershina, EA, Burlutskiy, NP, Pavlov, DI, Ryadun, AA, Fedin, VP & Potapov, AS 2022, 'Coordination Polymers of Cadmium with Di(pyrazol-1-yl)alkane-4,4'-dicarboxylic Acids: Synthesis, Crystal Structures, and Luminescence Properties', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, том. 48, № 10, стр. 601-607. https://doi.org/10.1134/S1070328422100049

Coordination Polymers of Cadmium with Di(pyrazol-1-yl)alkane-4,4'-dicarboxylic Acids: Synthesis, Crystal Structures, and Luminescence Properties. / Pershina, E. A.; Burlutskiy, N. P.; Pavlov, D. I. и др.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 48, № 10, 10.2022, стр. 601-607.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Coordination Polymers of Cadmium with Di(pyrazol-1-yl)alkane-4,4'-dicarboxylic Acids: Synthesis, Crystal Structures, and Luminescence Properties

AU - Pershina, E. A.

AU - Burlutskiy, N. P.

AU - Pavlov, D. I.

AU - Ryadun, A. A.

AU - Fedin, V. P.

AU - Potapov, A. S.

N1 - Funding Information: This work was supported by the Committee of Science of the Ministry of Education and Science of Kazakhstan (grant no. AP08856049). The physicochemical characterization of the synthesized compounds was carried out at the Center for Collective Use at the Nikolaev Institute of Inorganic Chemistry (Siberian Branch, Russian Academy of Sciences) and supported by the Ministry of Science and Higher Education of the Russian Federation (projects nos. 121031700321-3 and 121031700313-8). Publisher Copyright: © 2022, Pleiades Publishing, Ltd.

PY - 2022/10

Y1 - 2022/10

N2 - Coordination polymers of cadmium(II) with the di(pyrazol-1-yl)alkane derivatives, bis(3,5-dimethylpyrazol-1-yl)methane-4,4′-dicarboxylic acid (H2L1) and 1,3-bis(pyrazol-1-yl)propane-4,4′-dicarboxylic acid (H2L2), are synthesized. The crystal structures of the products are determined by X-ray diffraction (CIF files CCDC nos. 2172853 (I) and 2172854 (II)). The Cd2+ ions and dicarboxylic acid with one methylene group between the pyrazole cycles form a three-dimensional coordination polymer with a single mutual intergrowing of coordination networks, whereas three methylene groups result in the formation of a two-dimensional coordination polymer, the layers of which are linked by hydrogen bonds involving water molecules in the coordination sphere of the Cd2+ ions. The luminescence spectra of the synthesized coordination polymers exhibit two bands: with the local intraligand excitation and with the metal–ligand charge transfer.

AB - Coordination polymers of cadmium(II) with the di(pyrazol-1-yl)alkane derivatives, bis(3,5-dimethylpyrazol-1-yl)methane-4,4′-dicarboxylic acid (H2L1) and 1,3-bis(pyrazol-1-yl)propane-4,4′-dicarboxylic acid (H2L2), are synthesized. The crystal structures of the products are determined by X-ray diffraction (CIF files CCDC nos. 2172853 (I) and 2172854 (II)). The Cd2+ ions and dicarboxylic acid with one methylene group between the pyrazole cycles form a three-dimensional coordination polymer with a single mutual intergrowing of coordination networks, whereas three methylene groups result in the formation of a two-dimensional coordination polymer, the layers of which are linked by hydrogen bonds involving water molecules in the coordination sphere of the Cd2+ ions. The luminescence spectra of the synthesized coordination polymers exhibit two bands: with the local intraligand excitation and with the metal–ligand charge transfer.

KW - cadmium

KW - coordination polymers

KW - dicarboxylic acids

KW - luminescence

KW - pyrazole

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DO - 10.1134/S1070328422100049

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JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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