Аннотация
A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.
Язык оригинала | английский |
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Страницы (с-по) | 10319-10327 |
Число страниц | 9 |
Журнал | Chemistry - A European Journal |
Том | 23 |
Номер выпуска | 43 |
DOI | |
Состояние | Опубликовано - 1 авг 2017 |