Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids

Andreas E. Seitz, Ulf Vogel, Miriam Eberl, Maria Eckhardt, Gábor Balázs, Eugenia V. Peresypkina, Michael Bodensteiner, Manfred Zabel, Manfred Scheer

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование

7 Цитирования (Scopus)


A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.

Язык оригиналаанглийский
Страницы (с-по)10319-10327
Число страниц9
ЖурналChemistry - A European Journal
Номер выпуска43
СостояниеОпубликовано - 1 авг. 2017


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