Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids

Andreas E. Seitz; Ulf Vogel; Miriam Eberl; Maria Eckhardt; Gábor Balázs; Eugenia V. Peresypkina; Michael Bodensteiner; Manfred Zabel; Manfred Scheer

doi:10.1002/chem.201701380

Coordination Behavior of [Cp′′₂Zr(η^1:1-P₄)] towards Different Lewis Acids

Andreas E. Seitz, Ulf Vogel, Miriam Eberl, Maria Eckhardt, Gábor Balázs, Eugenia V. Peresypkina, Michael Bodensteiner, Manfred Zabel, Manfred Scheer

Лаборатория методов исследования состава и структуры функциональных материалов ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

7 Цитирования (Scopus)

Аннотация

A detailed method for the preparation of [Cp′′₂Zr(η^1:1-P₄)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe₃, AlEt₃) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.

Язык оригинала	английский
Страницы (с-по)	10319-10327
Число страниц	9
Журнал	Chemistry - A European Journal
Том	23
Номер выпуска	43
DOI	https://doi.org/10.1002/chem.201701380
Состояние	Опубликовано - 1 авг 2017

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10.1002/chem.201701380

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title = "Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids",

abstract = "A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.",

keywords = "coordination chemistry, DFT calculations, Lewis acids, NMR spectroscopy, phosphorus, TETRAHEDRO-TETRAPHOSPHORUS, TRANSITION-METAL-COMPLEXES, MOLECULAR-STRUCTURE, LIGAND COMPLEXES, P-4 ACTIVATION, ELEMENTS, CYCLO-TRIPHOSPHORUS, DINITROGEN, CHEMISTRY, WHITE PHOSPHORUS",

author = "Seitz, {Andreas E.} and Ulf Vogel and Miriam Eberl and Maria Eckhardt and G{\'a}bor Bal{\'a}zs and Peresypkina, {Eugenia V.} and Michael Bodensteiner and Manfred Zabel and Manfred Scheer",

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Coordination Behavior of [Cp′′₂Zr(η^1:1-P₄)] towards Different Lewis Acids. / Seitz, Andreas E.; Vogel, Ulf; Eberl, Miriam; Eckhardt, Maria; Balázs, Gábor; Peresypkina, Eugenia V.; Bodensteiner, Michael; Zabel, Manfred; Scheer, Manfred.

В: Chemistry - A European Journal, Том 23, № 43, 01.08.2017, стр. 10319-10327.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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AU - Seitz, Andreas E.

AU - Vogel, Ulf

AU - Eberl, Miriam

AU - Eckhardt, Maria

AU - Balázs, Gábor

AU - Peresypkina, Eugenia V.

AU - Bodensteiner, Michael

AU - Zabel, Manfred

AU - Scheer, Manfred

PY - 2017/8/1

Y1 - 2017/8/1

N2 - A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.

AB - A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.

KW - coordination chemistry

KW - DFT calculations

KW - Lewis acids

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KW - phosphorus

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KW - TRANSITION-METAL-COMPLEXES

KW - MOLECULAR-STRUCTURE

KW - LIGAND COMPLEXES

KW - P-4 ACTIVATION

KW - ELEMENTS

KW - CYCLO-TRIPHOSPHORUS

KW - DINITROGEN

KW - CHEMISTRY

KW - WHITE PHOSPHORUS

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