Configurational Stability of 1,1′-Bi-2-naphthol in Superacid System HSO3F–SbF5–SO2ClF

G. E. Salnikov; A. M. Genaev; A. V. Shernyukov; Z. Zhu; N. V. Tkachenko; K. Yu Koltunov

doi:10.1134/S1070428018050214

Configurational Stability of 1,1′-Bi-2-naphthol in Superacid System HSO₃F–SbF₅–SO₂ClF

G. E. Salnikov, A. M. Genaev, A. V. Shernyukov, Z. Zhu, N. V. Tkachenko, K. Yu Koltunov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

Although 1,1′-bi-2-naphthol (BINOL) is known to racemize in aqueous mineral acids and much more readily in superacids, it retains its initial configuration in one of the strongest superacid system, HSO₃F-SbF₅-SO₂ClF due to protective C⁸,C^8′-diprotonation.

Язык оригинала	английский
Страницы (с-по)	792-794
Число страниц	3
Журнал	Russian Journal of Organic Chemistry
Том	54
Номер выпуска	5
DOI	https://doi.org/10.1134/S1070428018050214
Состояние	Опубликовано - 1 мая 2018

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10.1134/S1070428018050214

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abstract = "Although 1,1′-bi-2-naphthol (BINOL) is known to racemize in aqueous mineral acids and much more readily in superacids, it retains its initial configuration in one of the strongest superacid system, HSO3F-SbF5-SO2ClF due to protective C8,C8′-diprotonation.",

author = "Salnikov, {G. E.} and Genaev, {A. M.} and Shernyukov, {A. V.} and Z. Zhu and Tkachenko, {N. V.} and Koltunov, {K. Yu}",

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Configurational Stability of 1,1′-Bi-2-naphthol in Superacid System HSO₃F–SbF₅–SO₂ClF. / Salnikov, G. E.; Genaev, A. M.; Shernyukov, A. V.; Zhu, Z.; Tkachenko, N. V.; Koltunov, K. Yu.

В: Russian Journal of Organic Chemistry, Том 54, № 5, 01.05.2018, стр. 792-794.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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AU - Shernyukov, A. V.

AU - Zhu, Z.

AU - Tkachenko, N. V.

AU - Koltunov, K. Yu

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AB - Although 1,1′-bi-2-naphthol (BINOL) is known to racemize in aqueous mineral acids and much more readily in superacids, it retains its initial configuration in one of the strongest superacid system, HSO3F-SbF5-SO2ClF due to protective C8,C8′-diprotonation.

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