Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF

A. V. Chupina; A. A. Mukhacheva; P. A. Abramov; M. N. Sokolov

doi:10.1134/S0022476620020158

Complexation and Isomerization of [β-Mo₈O₂₆]⁴⁻ in the Presence of Ag⁺ and DMF

A. V. Chupina, A. A. Mukhacheva, P. A. Abramov, M. N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag⁺ cation, and organic ligands: (Bu₄N)₈[Mo₈O₂₆Ag₂(DMF)_3.6(N₂S₃C₄H₆)_0.2]₂[Mo₈O₂₆Ag₂(DMF)(N₂S₃C₄H₆)]₂(1), (Bu₄N)₄[Mo₈O₂₆Ag₂(DMF)₄][Mo₈O₂₆Ag₂(DMF)₂] (2), (Bu₄N)₃[Mo₈O₂₆Ag₂(NO₃)(DMF)] (3), (Bu₄N)₄× ×[α-Mo₈O₂₆]·1,4DMF (4), and (Bu₄N)₄ [α-Mo₈O₂₆]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.

Язык оригинала	английский
Страницы (с-по)	299-308
Число страниц	10
Журнал	Journal of Structural Chemistry
Том	61
Номер выпуска	2
DOI	https://doi.org/10.1134/S0022476620020158
Состояние	Опубликовано - 1 февр. 2020

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@article{a499488dbedc40acbac87e0e8faa83da,

title = "Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF",

abstract = "In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.",

keywords = "crystal structure, octamolybdate, silver, OXIDATION, CLUSTERS, CRYSTAL-STRUCTURE, POLYOXOMETALATE, COORDINATION",

author = "Chupina, {A. V.} and Mukhacheva, {A. A.} and Abramov, {P. A.} and Sokolov, {M. N.}",

year = "2020",

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doi = "10.1134/S0022476620020158",

language = "English",

volume = "61",

pages = "299--308",

journal = "Journal of Structural Chemistry",

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}

Complexation and Isomerization of [β-Mo₈O₂₆]⁴⁻ in the Presence of Ag⁺ and DMF. / Chupina, A. V.; Mukhacheva, A. A.; Abramov, P. A. и др.

В: Journal of Structural Chemistry, Том 61, № 2, 01.02.2020, стр. 299-308.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF

AU - Chupina, A. V.

AU - Mukhacheva, A. A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2020/2/1

Y1 - 2020/2/1

N2 - In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.

AB - In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.

KW - crystal structure

KW - octamolybdate

KW - silver

KW - OXIDATION

KW - CLUSTERS

KW - CRYSTAL-STRUCTURE

KW - POLYOXOMETALATE

KW - COORDINATION

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DO - 10.1134/S0022476620020158

M3 - Article

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JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

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