Cluster aqua/hydroxocomplexes supporting extended hydrogen bonding networks. Preparation and structure of a unique series of cluster hydrates [Mo6I8(OH)4(H2O)2]·nH2O (n = 2, 12, 14)

Maxim A. Mikhaylov; Pavel A. Abramov; Vladislav Y. Komarov; Maxim N. Sokolov

doi:10.1016/j.poly.2016.11.011

Cluster aqua/hydroxocomplexes supporting extended hydrogen bonding networks. Preparation and structure of a unique series of cluster hydrates [Mo₆I₈(OH)₄(H₂O)₂]·nH₂O (n = 2, 12, 14)

Maxim A. Mikhaylov, Pavel A. Abramov, Vladislav Y. Komarov, Maxim N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

12 Цитирования (Scopus)

Аннотация

Isolation and structural characterization of three hydrates of a unique series of cluster hydrates [Mo₆I₈(OH)₄(H₂O)₂]·nH₂O (n = 14 (h₁₄), 12 (h₁₂), 2 (h₂)) by controlled hydrolysis of [K(diglyme)(CH₃CN)]₂[Mo₆I₁₄] in borate buffer solutions is reported. The structures of h₁₄ and h₁₂ feature three-dimensional hydrogen bond-based frameworks. In particular, the framework in h₁₂ is close to the frameworks observed in classical clathrate hydrates. In the structure of h₂ the water of crystallization forms discrete (H₂O)₂ dimers.

Язык оригинала	английский
Страницы (с-по)	241-246
Число страниц	6
Журнал	Polyhedron
Том	122
DOI	https://doi.org/10.1016/j.poly.2016.11.011
Состояние	Опубликовано - 1 янв 2017

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10.1016/j.poly.2016.11.011

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title = "Cluster aqua/hydroxocomplexes supporting extended hydrogen bonding networks. Preparation and structure of a unique series of cluster hydrates [Mo6I8(OH)4(H2O)2]·nH2O (n = 2, 12, 14)",

abstract = "Isolation and structural characterization of three hydrates of a unique series of cluster hydrates [Mo6I8(OH)4(H2O)2]·nH2O (n = 14 (h14), 12 (h12), 2 (h2)) by controlled hydrolysis of [K(diglyme)(CH3CN)]2[Mo6I14] in borate buffer solutions is reported. The structures of h14 and h12 feature three-dimensional hydrogen bond-based frameworks. In particular, the framework in h12 is close to the frameworks observed in classical clathrate hydrates. In the structure of h2 the water of crystallization forms discrete (H2O)2 dimers.",

keywords = "Aquacomplexes, Clathrate, Hydrates, Hydrolysis, Octahedral Mo clusters, BR, SE, LUMINESCENCE, BRIDGING LIGAND, COMPLEXES, CL, FAMILY",

author = "Mikhaylov, {Maxim A.} and Abramov, {Pavel A.} and Komarov, {Vladislav Y.} and Sokolov, {Maxim N.}",

year = "2017",

month = jan,

day = "1",

doi = "10.1016/j.poly.2016.11.011",

language = "English",

volume = "122",

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journal = "Polyhedron",

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publisher = "Elsevier",

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Cluster aqua/hydroxocomplexes supporting extended hydrogen bonding networks. Preparation and structure of a unique series of cluster hydrates [Mo₆I₈(OH)₄(H₂O)₂]·nH₂O (n = 2, 12, 14). / Mikhaylov, Maxim A.; Abramov, Pavel A.; Komarov, Vladislav Y.; Sokolov, Maxim N.

В: Polyhedron, Том 122, 01.01.2017, стр. 241-246.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Cluster aqua/hydroxocomplexes supporting extended hydrogen bonding networks. Preparation and structure of a unique series of cluster hydrates [Mo6I8(OH)4(H2O)2]·nH2O (n = 2, 12, 14)

AU - Mikhaylov, Maxim A.

AU - Abramov, Pavel A.

AU - Komarov, Vladislav Y.

AU - Sokolov, Maxim N.

PY - 2017/1/1

Y1 - 2017/1/1

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AB - Isolation and structural characterization of three hydrates of a unique series of cluster hydrates [Mo6I8(OH)4(H2O)2]·nH2O (n = 14 (h14), 12 (h12), 2 (h2)) by controlled hydrolysis of [K(diglyme)(CH3CN)]2[Mo6I14] in borate buffer solutions is reported. The structures of h14 and h12 feature three-dimensional hydrogen bond-based frameworks. In particular, the framework in h12 is close to the frameworks observed in classical clathrate hydrates. In the structure of h2 the water of crystallization forms discrete (H2O)2 dimers.

KW - Aquacomplexes

KW - Clathrate

KW - Hydrates

KW - Hydrolysis

KW - Octahedral Mo clusters

KW - BR

KW - SE

KW - LUMINESCENCE

KW - BRIDGING LIGAND

KW - COMPLEXES

KW - CL

KW - FAMILY

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M3 - Article

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EP - 246

JO - Polyhedron

JF - Polyhedron

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