Аннотация

Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′-propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two-dimensional polyhalide supramolecular networks. The nature of non-covalent Br···Cl interactions was studied by theoretical methods; estimated energies of these interactions are 1.9–6.0 kcal/mol.

Язык оригиналаанглийский
Страницы (с-по)4925-4929
Число страниц5
ЖурналEuropean Journal of Inorganic Chemistry
Том2017
Номер выпуска42
DOI
СостояниеОпубликовано - 16 ноя 2017

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