Catalytic enantioselective oxygen transfer reactions have been a long-standing goal of synthetic chemistry. The use of molecular oxygen in these oxidations has engaged significant research efforts for decades. The present review considers the state of the art of aerobic asymmetric oxidations mediated by chiral organocatalysts and transition metal catalysts, occurring with formation of new C-O bonds, i.e. Oxygenations. The milestones and limitations of existing approaches are discussed, with focus on catalyst design and catalytic performance. The bibliography includes 41 references.

Язык оригиналаанглийский
Страницы (с-по)821-830
Число страниц10
ЖурналRussian Chemical Reviews
Номер выпуска9
СостояниеОпубликовано - 1 янв. 2018


Подробные сведения о темах исследования «Catalytic asymmetric oxidations using molecular oxygen». Вместе они формируют уникальный семантический отпечаток (fingerprint).