Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks

Sergey A. Adonin; Mikhail A. Bondarenko; Pavel A. Abramov; Alexander S. Novikov; Pavel E. Plyusnin; Maxim N. Sokolov; Vladimir P. Fedin

doi:10.1002/chem.201801338

Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks

Sergey A. Adonin, Mikhail A. Bondarenko, Pavel A. Abramov, Alexander S. Novikov, Pavel E. Plyusnin, Maxim N. Sokolov, Vladimir P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

28 Цитирования (Scopus)

Аннотация

Cation-dependent reactions “[SbBr₆]³⁻+Br₂+HBr+CationBr_x” result in the formation of bromide/polybromide complexes with zero-, one-, two-, or three-dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol⁻¹).

Язык оригинала	английский
Страницы (с-по)	10165-10170
Число страниц	6
Журнал	Chemistry - A European Journal
Том	24
Номер выпуска	40
Ранняя дата в режиме онлайн	23 апр. 2018
DOI	https://doi.org/10.1002/chem.201801338
Состояние	Опубликовано - 17 июл. 2018

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10.1002/chem.201801338

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title = "Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks",

abstract = "Cation-dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero-, one-, two-, or three-dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1).",

keywords = "antimony, DFT calculations, halide complexes, non-covalent interactions, polyhalide",

author = "Adonin, {Sergey A.} and Bondarenko, {Mikhail A.} and Abramov, {Pavel A.} and Novikov, {Alexander S.} and Plyusnin, {Pavel E.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

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Bromo- and Polybromoantimonates(V) : Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks. / Adonin, Sergey A.; Bondarenko, Mikhail A.; Abramov, Pavel A. и др.

В: Chemistry - A European Journal, Том 24, № 40, 17.07.2018, стр. 10165-10170.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Bromo- and Polybromoantimonates(V)

T2 - Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks

AU - Adonin, Sergey A.

AU - Bondarenko, Mikhail A.

AU - Abramov, Pavel A.

AU - Novikov, Alexander S.

AU - Plyusnin, Pavel E.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2018/7/17

Y1 - 2018/7/17

N2 - Cation-dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero-, one-, two-, or three-dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1).

AB - Cation-dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero-, one-, two-, or three-dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1).

KW - antimony

KW - DFT calculations

KW - halide complexes

KW - non-covalent interactions

KW - polyhalide

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SP - 10165

EP - 10170

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

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IS - 40

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