Bromine-rich complexes of bismuth: Experimental and theoretical studies

Sergey A. Adonin; Igor D. Gorokh; Alexander S. Novikov; Denis G. Samsonenko; Pavel E. Plyusnin; Maxim N. Sokolov; Vladimir P. Fedin

doi:10.1039/c7dt04779g

Bromine-rich complexes of bismuth: Experimental and theoretical studies

Sergey A. Adonin, Igor D. Gorokh, Alexander S. Novikov, Denis G. Samsonenko, Pavel E. Plyusnin, Maxim N. Sokolov, Vladimir P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

24 Цитирования (Scopus)

Аннотация

Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)₃[BiBr₅(Br₃)] (1), (H₂bpp){[BiBr₅](Br₂)} (2) and (3-ClPyH)₂{[BiBr₅](Br₂)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.

Язык оригинала	английский
Страницы (с-по)	2683-2689
Число страниц	7
Журнал	Dalton Transactions
Том	47
Номер выпуска	8
DOI	https://doi.org/10.1039/c7dt04779g
Состояние	Опубликовано - 28 фев 2018

Доступ к документу

10.1039/c7dt04779g

Link to publication in Scopus

Fingerprint Подробные сведения о темах исследования «Bromine-rich complexes of bismuth: Experimental and theoretical studies». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

@article{5b435f0329db4ec68ba4e8f2d2bc6baa,

title = "Bromine-rich complexes of bismuth: Experimental and theoretical studies",

abstract = "Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.",

keywords = "TEMPERATURE IONIC LIQUID, ZETA BASIS-SETS, CRYSTAL-STRUCTURE, PHENYLTRIMETHYLAMMONIUM SALTS, NONCOVALENT INTERACTIONS, CENTER-DOT, HALOGEN, NETWORKS, NONABROMOANTIMONATE(V), POLYBROMIDES",

author = "Adonin, {Sergey A.} and Gorokh, {Igor D.} and Novikov, {Alexander S.} and Samsonenko, {Denis G.} and Plyusnin, {Pavel E.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

year = "2018",

month = feb,

day = "28",

doi = "10.1039/c7dt04779g",

language = "English",

volume = "47",

pages = "2683--2689",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "8",

}

Bromine-rich complexes of bismuth : Experimental and theoretical studies. / Adonin, Sergey A.; Gorokh, Igor D.; Novikov, Alexander S.; Samsonenko, Denis G.; Plyusnin, Pavel E.; Sokolov, Maxim N.; Fedin, Vladimir P.

В: Dalton Transactions, Том 47, № 8, 28.02.2018, стр. 2683-2689.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Bromine-rich complexes of bismuth

T2 - Experimental and theoretical studies

AU - Adonin, Sergey A.

AU - Gorokh, Igor D.

AU - Novikov, Alexander S.

AU - Samsonenko, Denis G.

AU - Plyusnin, Pavel E.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2018/2/28

Y1 - 2018/2/28

N2 - Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.

AB - Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.

KW - TEMPERATURE IONIC LIQUID

KW - ZETA BASIS-SETS

KW - CRYSTAL-STRUCTURE

KW - PHENYLTRIMETHYLAMMONIUM SALTS

KW - NONCOVALENT INTERACTIONS

KW - CENTER-DOT

KW - HALOGEN

KW - NETWORKS

KW - NONABROMOANTIMONATE(V)

KW - POLYBROMIDES

UR - http://www.scopus.com/inward/record.url?scp=85042376329&partnerID=8YFLogxK

U2 - 10.1039/c7dt04779g

DO - 10.1039/c7dt04779g

M3 - Article

C2 - 29410985

AN - SCOPUS:85042376329

VL - 47

SP - 2683

EP - 2689

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 8

ER -