Bromine-rich complexes of bismuth: Experimental and theoretical studies

Sergey A. Adonin; Igor D. Gorokh; Alexander S. Novikov; Denis G. Samsonenko; Pavel E. Plyusnin; Maxim N. Sokolov; Vladimir P. Fedin

doi:10.1039/c7dt04779g

Bromine-rich complexes of bismuth: Experimental and theoretical studies

Sergey A. Adonin, Igor D. Gorokh, Alexander S. Novikov, Denis G. Samsonenko, Pavel E. Plyusnin, Maxim N. Sokolov, Vladimir P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья

20 Цитирования (Scopus)

Аннотация

Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)₃[BiBr₅(Br₃)] (1), (H₂bpp){[BiBr₅](Br₂)} (2) and (3-ClPyH)₂{[BiBr₅](Br₂)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.

Язык оригинала	английский
Страницы (с-по)	2683-2689
Число страниц	7
Журнал	Dalton Transactions
Том	47
Номер выпуска	8
DOI	https://doi.org/10.1039/c7dt04779g
Состояние	Опубликовано - 28 фев 2018

Доступ к документу

10.1039/c7dt04779g

Link to publication in Scopus

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Цитировать

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title = "Bromine-rich complexes of bismuth: Experimental and theoretical studies",

abstract = "Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.",

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author = "Adonin, {Sergey A.} and Gorokh, {Igor D.} and Novikov, {Alexander S.} and Samsonenko, {Denis G.} and Plyusnin, {Pavel E.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

year = "2018",

month = feb,

day = "28",

doi = "10.1039/c7dt04779g",

language = "English",

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journal = "Dalton Transactions",

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Bromine-rich complexes of bismuth : Experimental and theoretical studies. / Adonin, Sergey A.; Gorokh, Igor D.; Novikov, Alexander S.; Samsonenko, Denis G.; Plyusnin, Pavel E.; Sokolov, Maxim N.; Fedin, Vladimir P.

В: Dalton Transactions, Том 47, № 8, 28.02.2018, стр. 2683-2689.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

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AU - Adonin, Sergey A.

AU - Gorokh, Igor D.

AU - Novikov, Alexander S.

AU - Samsonenko, Denis G.

AU - Plyusnin, Pavel E.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

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AB - Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.

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KW - HALOGEN

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KW - NONABROMOANTIMONATE(V)

KW - POLYBROMIDES

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