@article{5b435f0329db4ec68ba4e8f2d2bc6baa,
title = "Bromine-rich complexes of bismuth: Experimental and theoretical studies",
abstract = "Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.",
keywords = "TEMPERATURE IONIC LIQUID, ZETA BASIS-SETS, CRYSTAL-STRUCTURE, PHENYLTRIMETHYLAMMONIUM SALTS, NONCOVALENT INTERACTIONS, CENTER-DOT, HALOGEN, NETWORKS, NONABROMOANTIMONATE(V), POLYBROMIDES",
author = "Adonin, {Sergey A.} and Gorokh, {Igor D.} and Novikov, {Alexander S.} and Samsonenko, {Denis G.} and Plyusnin, {Pavel E.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",
note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",
year = "2018",
month = feb,
day = "28",
doi = "10.1039/c7dt04779g",
language = "English",
volume = "47",
pages = "2683--2689",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "8",
}