Аннотация
Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.
Язык оригинала | английский |
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Страницы (с-по) | 2683-2689 |
Число страниц | 7 |
Журнал | Dalton Transactions |
Том | 47 |
Номер выпуска | 8 |
DOI | |
Состояние | Опубликовано - 28 фев 2018 |