Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity

A. N. Usol’tsev; M. D. Petrov; I. V. Korol’kov; M. N. Sokolov; V. A. Blatov; S. A. Adonin

doi:10.1134/S107032842108008X

Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity

A. N. Usol’tsev, M. D. Petrov, I. V. Korol’kov, M. N. Sokolov, V. A. Blatov, S. A. Adonin

Факультет естественных наук

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

The reaction of solutions of Sb₂O₃ and 4,4'-dimethyl-1,1'-butanediylbis(pyridinium) dibromide ((4-MePyC₄)Br₂) in concentrated HBr affords polymorphs: binuclear (4-MePyC₂)[Sb₂Br₈] (I) or tetranuclear (4-MePyC₄)₂[Sb₄Br₁₆] (II) complexes, depending on the reaction conditions. The structures of the complexes are studied by X-ray structure analysis (CIF files CCDC nos. 2061368 (I) and 2061369 (II)).

Язык оригинала	английский
Страницы (с-по)	620-625
Число страниц	6
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	47
Номер выпуска	9
DOI	https://doi.org/10.1134/S107032842108008X
Состояние	Опубликовано - сен 2021

Предметные области OECD FOS+WOS

2.04 ХИМИЧЕСКИЕ ТЕХНОЛОГИИ
1.04 ХИМИЧЕСКИЕ НАУКИ

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Usol’tsev, A. N., Petrov, M. D., Korol’kov, I. V., Sokolov, M. N., Blatov, V. A., & Adonin, S. A. (2021). Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 47(9), 620-625. https://doi.org/10.1134/S107032842108008X

Usol’tsev, A. N. ; Petrov, M. D. ; Korol’kov, I. V. ; Sokolov, M. N. ; Blatov, V. A. ; Adonin, S. A. / Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity. В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 ; Том 47, № 9. стр. 620-625.

@article{a2bfade917634f75b3ea4fb0dce0d169,

title = "Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity",

abstract = "The reaction of solutions of Sb2O3 and 4,4'-dimethyl-1,1'-butanediylbis(pyridinium) dibromide ((4-MePyC4)Br2) in concentrated HBr affords polymorphs: binuclear (4-MePyC2)[Sb2Br8] (I) or tetranuclear (4-MePyC4)2[Sb4Br16] (II) complexes, depending on the reaction conditions. The structures of the complexes are studied by X-ray structure analysis (CIF files CCDC nos. 2061368 (I) and 2061369 (II)).",

keywords = "antimony, bromide complexes, polymorphism, polynuclear complexes, X-ray structure analysis",

author = "Usol{\textquoteright}tsev, {A. N.} and Petrov, {M. D.} and Korol{\textquoteright}kov, {I. V.} and Sokolov, {M. N.} and Blatov, {V. A.} and Adonin, {S. A.}",

note = "Funding Information: This work was supported by the Russian Science Foundation, project no. 18-73-10040. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = sep,

doi = "10.1134/S107032842108008X",

language = "English",

volume = "47",

pages = "620--625",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "9",

}

Usol’tsev, AN, Petrov, MD, Korol’kov, IV, Sokolov, MN, Blatov, VA & Adonin, SA 2021, 'Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, том. 47, № 9, стр. 620-625. https://doi.org/10.1134/S107032842108008X

Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity. / Usol’tsev, A. N.; Petrov, M. D.; Korol’kov, I. V.; Sokolov, M. N.; Blatov, V. A.; Adonin, S. A.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 47, № 9, 09.2021, стр. 620-625.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity

AU - Usol’tsev, A. N.

AU - Petrov, M. D.

AU - Korol’kov, I. V.

AU - Sokolov, M. N.

AU - Blatov, V. A.

AU - Adonin, S. A.

PY - 2021/9

Y1 - 2021/9

N2 - The reaction of solutions of Sb2O3 and 4,4'-dimethyl-1,1'-butanediylbis(pyridinium) dibromide ((4-MePyC4)Br2) in concentrated HBr affords polymorphs: binuclear (4-MePyC2)[Sb2Br8] (I) or tetranuclear (4-MePyC4)2[Sb4Br16] (II) complexes, depending on the reaction conditions. The structures of the complexes are studied by X-ray structure analysis (CIF files CCDC nos. 2061368 (I) and 2061369 (II)).

AB - The reaction of solutions of Sb2O3 and 4,4'-dimethyl-1,1'-butanediylbis(pyridinium) dibromide ((4-MePyC4)Br2) in concentrated HBr affords polymorphs: binuclear (4-MePyC2)[Sb2Br8] (I) or tetranuclear (4-MePyC4)2[Sb4Br16] (II) complexes, depending on the reaction conditions. The structures of the complexes are studied by X-ray structure analysis (CIF files CCDC nos. 2061368 (I) and 2061369 (II)).

KW - antimony

KW - bromide complexes

KW - polymorphism

KW - polynuclear complexes

KW - X-ray structure analysis

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U2 - 10.1134/S107032842108008X

DO - 10.1134/S107032842108008X

M3 - Article

AN - SCOPUS:85114729813

VL - 47

SP - 620

EP - 625

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 9

ER -

Usol’tsev AN, Petrov MD, Korol’kov IV, Sokolov MN, Blatov VA, Adonin SA. Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 Сент.;47(9):620-625. https://doi.org/10.1134/S107032842108008X