Blocking {RhCl}2+ disorder in the crystal structure of a [SiW11O39{RhCl}]6− salt: Direct localization of the heterometal in a monosubstituted Keggin anion

Anna A. Mukhacheva, Victoria V. Volchek, Pavel A. Abramov, Maxim N. Sokolov

Результат исследования: Научные публикации в периодических изданияхстатья

1 Цитирования (Scopus)

Аннотация

Heating [γ-SiW10O36]8− with rhodium (II) acetate at 60 °C results in the formation of [SiW11O39{RhCl}]6−, isolated as K8[SiW11O39{RhCl}][Rh2(CH3COO)4Cl2]·8H2O (1). Unique feature of the crystal structure of 1 is fully ordered Keggin anion, allowing localization of the {RhCl}2+ fragment directly from X-ray diffraction data (Rh-Cl 2.212(5) Å Rh-O 1.96–2.13 Å). The product was also characterized by XRPD, IR and elemental analysis. According to coupled HPLC-ICP-AES technique the [SiW11O39{RhCl}]6− anion selectively forms in the reaction.

Язык оригиналаанглийский
Страницы (с-по)10-12
Число страниц3
ЖурналInorganic Chemistry Communications
Том89
DOI
СостояниеОпубликовано - 1 мар 2018

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