Blatter Radical-Decorated Silica as a Prospective Adsorbent for Selective NO Capture from Air

Artem S Poryvaev; Eva Gjuzi; Anastasiya A Yazikova; Daniil M Polyukhov; Yana N Albrekht; Aleksandr A Efremov; Nikita A Kudriavykh; Vadim V Yanshole; Frank Hoffmann; Michael Fröba; Matvey V Fedin

doi:10.1021/acsami.2c19183

Blatter Radical-Decorated Silica as a Prospective Adsorbent for Selective NO Capture from Air

Artem S Poryvaev, Eva Gjuzi, Anastasiya A Yazikova, Daniil M Polyukhov, Yana N Albrekht, Aleksandr A Efremov, Nikita A Kudriavykh, Vadim V Yanshole, Frank Hoffmann, Michael Fröba, Matvey V Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Nitrogen oxides are adverse poisonous gases present in the atmosphere and having detrimental effects on the human health and environment. In this work, we propose a new type of mesoporous materials capable of capturing nitrogen monoxide (NO) from air. The designed material combines the robust Santa Barbara Amorphous-15 silica scaffold and ultrastable Blatter-type radicals acting as NO traps. Using in situ electron paramagnetic resonance spectroscopy, we demonstrate that NO capture from air is selective and reversible at practical conditions, thus making Blatter radical-decorated silica highly promising for environmental applications.

Язык оригинала	английский
Страницы (с-по)	5191-5197
Число страниц	7
Журнал	ACS applied materials & interfaces
Том	15
Номер выпуска	4
Ранняя дата в режиме онлайн	18 янв. 2023
DOI	https://doi.org/10.1021/acsami.2c19183
Состояние	Опубликовано - 1 февр. 2023

Предметные области OECD FOS+WOS

2.05 ТЕХНОЛОГИЯ МАТЕРИАЛОВ

Доступ к документу

10.1021/acsami.2c19183

Другие файлы и ссылки

https://www.mendeley.com/catalogue/4fc3a29c-1413-3b26-acf0-86324decea10/

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@article{96480ef51b8c43abb0ba5d2c5ff34196,

title = "Blatter Radical-Decorated Silica as a Prospective Adsorbent for Selective NO Capture from Air",

abstract = "Nitrogen oxides are adverse poisonous gases present in the atmosphere and having detrimental effects on the human health and environment. In this work, we propose a new type of mesoporous materials capable of capturing nitrogen monoxide (NO) from air. The designed material combines the robust Santa Barbara Amorphous-15 silica scaffold and ultrastable Blatter-type radicals acting as NO traps. Using in situ electron paramagnetic resonance spectroscopy, we demonstrate that NO capture from air is selective and reversible at practical conditions, thus making Blatter radical-decorated silica highly promising for environmental applications.",

keywords = "Blatter radical, EPR spectroscopy, SBA-15, electron paramagnetic resonance, mesoporous silica, nitrogen monoxide capture",

author = "Poryvaev, {Artem S} and Eva Gjuzi and Yazikova, {Anastasiya A} and Polyukhov, {Daniil M} and Albrekht, {Yana N} and Efremov, {Aleksandr A} and Kudriavykh, {Nikita A} and Yanshole, {Vadim V} and Frank Hoffmann and Michael Fr{\"o}ba and Fedin, {Matvey V}",

note = "Funding: This work was funded by RFBR (no. 20-53-12005) and the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) - Projektnummer 429839772 in a DFG−RFBR collaborative project.",

year = "2023",

month = feb,

day = "1",

doi = "10.1021/acsami.2c19183",

language = "English",

volume = "15",

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journal = "ACS applied materials & interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "4",

}

Blatter Radical-Decorated Silica as a Prospective Adsorbent for Selective NO Capture from Air. / Poryvaev, Artem S; Gjuzi, Eva; Yazikova, Anastasiya A и др.

В: ACS applied materials & interfaces, Том 15, № 4, 01.02.2023, стр. 5191-5197.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Blatter Radical-Decorated Silica as a Prospective Adsorbent for Selective NO Capture from Air

AU - Poryvaev, Artem S

AU - Gjuzi, Eva

AU - Yazikova, Anastasiya A

AU - Polyukhov, Daniil M

AU - Albrekht, Yana N

AU - Efremov, Aleksandr A

AU - Kudriavykh, Nikita A

AU - Yanshole, Vadim V

AU - Hoffmann, Frank

AU - Fröba, Michael

AU - Fedin, Matvey V

N1 - Funding: This work was funded by RFBR (no. 20-53-12005) and the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) - Projektnummer 429839772 in a DFG−RFBR collaborative project.

PY - 2023/2/1

Y1 - 2023/2/1

N2 - Nitrogen oxides are adverse poisonous gases present in the atmosphere and having detrimental effects on the human health and environment. In this work, we propose a new type of mesoporous materials capable of capturing nitrogen monoxide (NO) from air. The designed material combines the robust Santa Barbara Amorphous-15 silica scaffold and ultrastable Blatter-type radicals acting as NO traps. Using in situ electron paramagnetic resonance spectroscopy, we demonstrate that NO capture from air is selective and reversible at practical conditions, thus making Blatter radical-decorated silica highly promising for environmental applications.

AB - Nitrogen oxides are adverse poisonous gases present in the atmosphere and having detrimental effects on the human health and environment. In this work, we propose a new type of mesoporous materials capable of capturing nitrogen monoxide (NO) from air. The designed material combines the robust Santa Barbara Amorphous-15 silica scaffold and ultrastable Blatter-type radicals acting as NO traps. Using in situ electron paramagnetic resonance spectroscopy, we demonstrate that NO capture from air is selective and reversible at practical conditions, thus making Blatter radical-decorated silica highly promising for environmental applications.

KW - Blatter radical

KW - EPR spectroscopy

KW - SBA-15

KW - electron paramagnetic resonance

KW - mesoporous silica

KW - nitrogen monoxide capture

UR - https://www.mendeley.com/catalogue/4fc3a29c-1413-3b26-acf0-86324decea10/

U2 - 10.1021/acsami.2c19183

DO - 10.1021/acsami.2c19183

M3 - Article

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VL - 15

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JO - ACS applied materials & interfaces

JF - ACS applied materials & interfaces

SN - 1944-8244

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ER -