Bis(dicyclohexylselenophosphinyl)selenide, [Cy2P(Se)]2Se: Synthesis, molecular structure and application for self-assembly of a tetrahedral Cu(I) cluster

Alexander V. Artem'ev, Evgeniya P. Doronina, Irina Yu Bagryanskaya, Lyudmila V. Klyba

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

The molecular structure of the selenides of [R2P(Se)]2Se type has been systematically studied on example of bis(dicyclohexylselenophosphinyl)selenide, [Cy2P(Se)]2Se. This selenide has been synthesized in 65% yield by oxidation of Cy2PH with elemental selenium in 1:2 M ratio. Its structure has been investigated by X-ray diffractometry (XRD), NMR, FT-IR and MALDI-TOF/MS techniques. In the solid, the Se1–P–Se2–P–Se3 chain of (Cy2P = Se)2Se molecule adopts a syn-anti conformation with the Se1–P–Se2–P and P–Se2–P–Se3 torsion angles of −179.64 (3)° and 4.69 (4)°. The vibrational band assignments, performing at B3LYP/6-311++G (d,p) theory level, are in a good agreement with the experimental FT-IR frequencies. The synthetic utility of the prepared selenide has been exemplified by its reaction with CuCl2 resulted in the formation of [Cu4(Se2PCy2)4] cluster in 53% yield. The structure of latter is formed by a Cu4 tetrahedron, wherein each triangular face is bridged by a [Se2PCy2] ligand in a trimetallic triconnective (μ2, μ1) pattern.

Язык оригиналаанглийский
Страницы (с-по)208-214
Число страниц7
ЖурналJournal of Molecular Structure
Том1160
DOI
СостояниеОпубликовано - 15 мая 2018

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