Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene

P. A. Petrov; E. A. Golubitskaya; N. B. Kompankov; I. V. Eltsov; T. S. Sukhikh; M. N. Sokolov

doi:10.1134/S0022476619120151

Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene

P. A. Petrov, E. A. Golubitskaya, N. B. Kompankov, I. V. Eltsov, T. S. Sukhikh, M. N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

By the interaction of Nb(NMe₂)₅ and 1,3-(2,6-diisopropylphenyl)imidazolium (IPr·HBF₄) tetrafluoroborate a binuclear complex with coordinated N-heterocyclic carbene [(IPr)Nb(=NMe)(NMe₂)(μ-F)₂(μ-NMe₂) NbF₂(NMe₂)] (1) is obtained. The reaction of Nb(NMe₂)₅ and 1,3-(2,4,6-trimethylphenyl)imidazolium (IMes·HBF₄) tetrafluoroborate yields [(IMes)₂H][NbF₆] salt (2). The structure of the complexes is determined by single crystal X-ray diffraction.

Язык оригинала	английский
Страницы (с-по)	1989-1994
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	12
DOI	https://doi.org/10.1134/S0022476619120151
Состояние	Опубликовано - 1 дек. 2019

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10.1134/S0022476619120151

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title = "Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene",

abstract = "By the interaction of Nb(NMe2)5 and 1,3-(2,6-diisopropylphenyl)imidazolium (IPr·HBF4) tetrafluoroborate a binuclear complex with coordinated N-heterocyclic carbene [(IPr)Nb(=NMe)(NMe2)(μ-F)2(μ-NMe2) NbF2(NMe2)] (1) is obtained. The reaction of Nb(NMe2)5 and 1,3-(2,4,6-trimethylphenyl)imidazolium (IMes·HBF4) tetrafluoroborate yields [(IMes)2H][NbF6] salt (2). The structure of the complexes is determined by single crystal X-ray diffraction.",

keywords = "amides, N-heterocyclic carbenes, niobium, single crystal XRD, TANTALUM, CHLORIDE",

author = "Petrov, {P. A.} and Golubitskaya, {E. A.} and Kompankov, {N. B.} and Eltsov, {I. V.} and Sukhikh, {T. S.} and Sokolov, {M. N.}",

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month = dec,

day = "1",

doi = "10.1134/S0022476619120151",

language = "English",

volume = "60",

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Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene. / Petrov, P. A.; Golubitskaya, E. A.; Kompankov, N. B. и др.

В: Journal of Structural Chemistry, Том 60, № 12, 01.12.2019, стр. 1989-1994.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene

AU - Petrov, P. A.

AU - Golubitskaya, E. A.

AU - Kompankov, N. B.

AU - Eltsov, I. V.

AU - Sukhikh, T. S.

AU - Sokolov, M. N.

PY - 2019/12/1

Y1 - 2019/12/1

N2 - By the interaction of Nb(NMe2)5 and 1,3-(2,6-diisopropylphenyl)imidazolium (IPr·HBF4) tetrafluoroborate a binuclear complex with coordinated N-heterocyclic carbene [(IPr)Nb(=NMe)(NMe2)(μ-F)2(μ-NMe2) NbF2(NMe2)] (1) is obtained. The reaction of Nb(NMe2)5 and 1,3-(2,4,6-trimethylphenyl)imidazolium (IMes·HBF4) tetrafluoroborate yields [(IMes)2H][NbF6] salt (2). The structure of the complexes is determined by single crystal X-ray diffraction.

AB - By the interaction of Nb(NMe2)5 and 1,3-(2,6-diisopropylphenyl)imidazolium (IPr·HBF4) tetrafluoroborate a binuclear complex with coordinated N-heterocyclic carbene [(IPr)Nb(=NMe)(NMe2)(μ-F)2(μ-NMe2) NbF2(NMe2)] (1) is obtained. The reaction of Nb(NMe2)5 and 1,3-(2,4,6-trimethylphenyl)imidazolium (IMes·HBF4) tetrafluoroborate yields [(IMes)2H][NbF6] salt (2). The structure of the complexes is determined by single crystal X-ray diffraction.

KW - amides

KW - N-heterocyclic carbenes

KW - niobium

KW - single crystal XRD

KW - TANTALUM

KW - CHLORIDE

UR - http://www.scopus.com/inward/record.url?scp=85077602792&partnerID=8YFLogxK

U2 - 10.1134/S0022476619120151

DO - 10.1134/S0022476619120151

M3 - Article

AN - SCOPUS:85077602792

VL - 60

SP - 1989

EP - 1994

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

ER -

Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene

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