Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S                         
                        2
                                                 CNPr                         
                        2
                                                 )                         
                        2
                                                 ][AgCl                         
                        2
                                                 ])                         
                        n

E. V. Korneeva; A. I. Smolentsev; O. N. Antzutkin; A. V. Ivanov

doi:10.1007/s11172-019-2413-7

Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S ₂ CNPr ₂ ) ₂ ][AgCl ₂ ]) _n

E. V. Korneeva, A. I. Smolentsev, O. N. Antzutkin, A. V. Ivanov

Лаборатория полиядерных координационных соединений ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

4 Цитирования (Scopus)

Аннотация

The double ionic-polymer complex ([Au(S ₂ CNPr ₂ ) ₂ ][AgCl ₂ ]) _n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and ¹³ C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S ₂ CNPr ₂ ) ₂ ] ⁺ (A and B) and the discrete linear anion [AgCl ₂ ] ^– . Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl ₂ ] ^– anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl ₂ ] ^– anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.

Язык оригинала	английский
Страницы (с-по)	40-47
Число страниц	8
Журнал	Russian Chemical Bulletin
Том	68
Номер выпуска	1
DOI	https://doi.org/10.1007/s11172-019-2413-7
Состояние	Опубликовано - 1 янв 2019

Доступ к документу

10.1007/s11172-019-2413-7

Link to publication in Scopus

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Цитировать

Korneeva, E. V., Smolentsev, A. I., Antzutkin, O. N., & Ivanov, A. V. (2019). Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S ₂ CNPr ₂ ) ₂ ][AgCl ₂ ]) _n. Russian Chemical Bulletin, 68(1), 40-47. https://doi.org/10.1007/s11172-019-2413-7

Korneeva, E. V. ; Smolentsev, A. I. ; Antzutkin, O. N. ; Ivanov, A. V. / Binding of gold(iii) with silver(i) dipropyldithiocarbamate : supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S ₂ CNPr ₂ ) ₂ ][AgCl ₂ ]) _n. В: Russian Chemical Bulletin. 2019 ; Том 68, № 1. стр. 40-47.

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title = "Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n",

abstract = " The double ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13 C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S 2 CNPr 2 ) 2 ] + (A and B) and the discrete linear anion [AgCl 2 ] – . Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl 2 ] – anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl 2 ] – anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis. ",

keywords = "C MAS NMR spectroscopy, binary complexes, dialkyldithiocarbamates, gold silver compounds, noble metals, secondary interactions, supramolecular self-assembly, thermal behavior, THIN-FILMS, C3H7, MOLECULAR-STRUCTURE, DEPOSITION, CRYSTAL, STRUCTURAL ORGANIZATION, C-13 MAS NMR spectroscopy, POLYNUCLEAR, C-13 NMR",

author = "Korneeva, {E. V.} and Smolentsev, {A. I.} and Antzutkin, {O. N.} and Ivanov, {A. V.}",

year = "2019",

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doi = "10.1007/s11172-019-2413-7",

language = "English",

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Korneeva, EV, Smolentsev, AI, Antzutkin, ON & Ivanov, AV 2019, 'Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S ₂ CNPr ₂ ) ₂ ][AgCl ₂ ]) _n', Russian Chemical Bulletin, том. 68, № 1, стр. 40-47. https://doi.org/10.1007/s11172-019-2413-7

Binding of gold(iii) with silver(i) dipropyldithiocarbamate : supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S ₂ CNPr ₂ ) ₂ ][AgCl ₂ ]) _n. / Korneeva, E. V.; Smolentsev, A. I.; Antzutkin, O. N.; Ivanov, A. V.

В: Russian Chemical Bulletin, Том 68, № 1, 01.01.2019, стр. 40-47.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Binding of gold(iii) with silver(i) dipropyldithiocarbamate

T2 - supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n

AU - Korneeva, E. V.

AU - Smolentsev, A. I.

AU - Antzutkin, O. N.

AU - Ivanov, A. V.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - The double ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13 C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S 2 CNPr 2 ) 2 ] + (A and B) and the discrete linear anion [AgCl 2 ] – . Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl 2 ] – anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl 2 ] – anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.

AB - The double ionic-polymer complex ([Au(S 2 CNPr 2 ) 2 ][AgCl 2 ]) n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13 C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S 2 CNPr 2 ) 2 ] + (A and B) and the discrete linear anion [AgCl 2 ] – . Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl 2 ] – anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl 2 ] – anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.

KW - C MAS NMR spectroscopy

KW - binary complexes

KW - dialkyldithiocarbamates

KW - gold silver compounds

KW - noble metals

KW - secondary interactions

KW - supramolecular self-assembly

KW - thermal behavior

KW - THIN-FILMS

KW - C3H7

KW - MOLECULAR-STRUCTURE

KW - DEPOSITION

KW - CRYSTAL

KW - STRUCTURAL ORGANIZATION

KW - C-13 MAS NMR spectroscopy

KW - POLYNUCLEAR

KW - C-13 NMR

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U2 - 10.1007/s11172-019-2413-7

DO - 10.1007/s11172-019-2413-7

M3 - Article

AN - SCOPUS:85064434277

VL - 68

SP - 40

EP - 47

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

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Korneeva EV, Smolentsev AI, Antzutkin ON, Ivanov AV. Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S ₂ CNPr ₂ ) ₂ ][AgCl ₂ ]) _n. Russian Chemical Bulletin. 2019 Янв. 1;68(1):40-47. https://doi.org/10.1007/s11172-019-2413-7