Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole

Dmitry I. Konovalov, Anton A. Ivanov, Yuri A. Vorotnikov, Konstantin A. Brylev, Ilia V. Eltsov, Vadim V. Yanshole, Natalia V. Kuratieva, Noboru Kitamura, Michael A. Shestopalov

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re6Q8}(3-Me-pzH)6]2+, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (1H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re6Q8}2+ core-centered nature of emission.

Язык оригиналаанглийский
Номер статьи119738
Число страниц5
ЖурналInorganica Chimica Acta
Том510
DOI
СостояниеОпубликовано - 24 сен 2020

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