@article{5cd3913e582145c391b48478b7e4f7df,
title = "Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole",
abstract = "Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re6Q8}(3-Me-pzH)6]2+, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (1H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re6Q8}2+ core-centered nature of emission.",
keywords = "3-methylpyrazole, Crystal structure, Luminescence, Rhenium cluster, SUPRAMOLECULAR ARRAYS, Q=S, HEXARHENIUM(III) CLUSTERS, SE, LUMINESCENCE, LIGANDS, SOLIDS, REDOX, METAL, EMISSION",
author = "Konovalov, {Dmitry I.} and Ivanov, {Anton A.} and Vorotnikov, {Yuri A.} and Brylev, {Konstantin A.} and Eltsov, {Ilia V.} and Yanshole, {Vadim V.} and Kuratieva, {Natalia V.} and Noboru Kitamura and Shestopalov, {Michael A.}",
note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = sep,
day = "24",
doi = "10.1016/j.ica.2020.119738",
language = "English",
volume = "510",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",
}