Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole

Dmitry I. Konovalov; Anton A. Ivanov; Yuri A. Vorotnikov; Konstantin A. Brylev; Ilia V. Eltsov; Vadim V. Yanshole; Natalia V. Kuratieva; Noboru Kitamura; Michael A. Shestopalov

doi:10.1016/j.ica.2020.119738

Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole

Dmitry I. Konovalov, Anton A. Ivanov, Yuri A. Vorotnikov, Konstantin A. Brylev, Ilia V. Eltsov, Vadim V. Yanshole, Natalia V. Kuratieva, Noboru Kitamura, Michael A. Shestopalov

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re₆Q₈}(3-Me-pzH)₆]²⁺, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (¹H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re₆Q₈}²⁺ core-centered nature of emission.

Язык оригинала	английский
Номер статьи	119738
Число страниц	5
Журнал	Inorganica Chimica Acta
Том	510
DOI	https://doi.org/10.1016/j.ica.2020.119738
Состояние	Опубликовано - 24 сен 2020

Доступ к документу

10.1016/j.ica.2020.119738

Link to publication in Scopus

Fingerprint Подробные сведения о темах исследования «Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

Konovalov, D. I., Ivanov, A. A., Vorotnikov, Y. A., Brylev, K. A., Eltsov, I. V., Yanshole, V. V., Kuratieva, N. V., Kitamura, N., & Shestopalov, M. A. (2020). Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole. Inorganica Chimica Acta, 510, [119738]. https://doi.org/10.1016/j.ica.2020.119738

@article{5cd3913e582145c391b48478b7e4f7df,

title = "Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole",

abstract = "Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re6Q8}(3-Me-pzH)6]2+, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (1H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re6Q8}2+ core-centered nature of emission.",

keywords = "3-methylpyrazole, Crystal structure, Luminescence, Rhenium cluster, SUPRAMOLECULAR ARRAYS, Q=S, HEXARHENIUM(III) CLUSTERS, SE, LUMINESCENCE, LIGANDS, SOLIDS, REDOX, METAL, EMISSION",

author = "Konovalov, {Dmitry I.} and Ivanov, {Anton A.} and Vorotnikov, {Yuri A.} and Brylev, {Konstantin A.} and Eltsov, {Ilia V.} and Yanshole, {Vadim V.} and Kuratieva, {Natalia V.} and Noboru Kitamura and Shestopalov, {Michael A.}",

year = "2020",

month = sep,

day = "24",

doi = "10.1016/j.ica.2020.119738",

language = "English",

volume = "510",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

}

Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole. / Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A.; Brylev, Konstantin A.; Eltsov, Ilia V.; Yanshole, Vadim V.; Kuratieva, Natalia V.; Kitamura, Noboru; Shestopalov, Michael A.

В: Inorganica Chimica Acta, Том 510, 119738, 24.09.2020.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole

AU - Konovalov, Dmitry I.

AU - Ivanov, Anton A.

AU - Vorotnikov, Yuri A.

AU - Brylev, Konstantin A.

AU - Eltsov, Ilia V.

AU - Yanshole, Vadim V.

AU - Kuratieva, Natalia V.

AU - Kitamura, Noboru

AU - Shestopalov, Michael A.

PY - 2020/9/24

Y1 - 2020/9/24

N2 - Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re6Q8}(3-Me-pzH)6]2+, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (1H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re6Q8}2+ core-centered nature of emission.

AB - Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re6Q8}(3-Me-pzH)6]2+, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (1H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re6Q8}2+ core-centered nature of emission.

KW - 3-methylpyrazole

KW - Crystal structure

KW - Luminescence

KW - Rhenium cluster

KW - SUPRAMOLECULAR ARRAYS

KW - Q=S

KW - HEXARHENIUM(III) CLUSTERS

KW - SE

KW - LUMINESCENCE

KW - LIGANDS

KW - SOLIDS

KW - REDOX

KW - METAL

KW - EMISSION

UR - http://www.scopus.com/inward/record.url?scp=85084301345&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2020.119738

DO - 10.1016/j.ica.2020.119738

M3 - Article

AN - SCOPUS:85084301345

VL - 510

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 119738

ER -