Antimony (V) Complex Halides: Lead-Free Perovskite-Like Materials for Hybrid Solar Cells

Sergey A. Adonin; Lyubov A. Frolova; Maxim N. Sokolov; Gennady V. Shilov; Denis V. Korchagin; Vladimir P. Fedin; Sergey M. Aldoshin; Keith J. Stevenson; Pavel A. Troshin

doi:10.1002/aenm.201701140

Antimony (V) Complex Halides: Lead-Free Perovskite-Like Materials for Hybrid Solar Cells

Sergey A. Adonin, Lyubov A. Frolova, Maxim N. Sokolov, Gennady V. Shilov, Denis V. Korchagin, Vladimir P. Fedin, Sergey M. Aldoshin, Keith J. Stevenson, Pavel A. Troshin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

55 Цитирования (Scopus)

Аннотация

Using bromoantimonate (V) (N-EtPy)[SbBr₆] as an example, it is demonstrated that ABX₆ compounds can form perovskite-like 3D crystalline frameworks with short interhalide contacts, enabling advanced optoelectronic characteristics of these materials. The designed compound shows an impressive performance in planar junction solar cells delivering external quantum efficiency of ≈80% and power conversion efficiency of ≈4%, thus being comparable with the conventional perovskite material MAPbBr₃. The discovery of the first perovskite-like compound ABX₆ exhibiting good photovoltaic performance opens wide opportunities for rational design of novel perovskite-like semiconductor materials for advanced electronic and photovoltaic applications.

Язык оригинала	английский
Номер статьи	1701140
Число страниц	6
Журнал	Advanced Energy Materials
Том	8
Номер выпуска	6
DOI	https://doi.org/10.1002/aenm.201701140
Состояние	Опубликовано - 26 февр. 2018

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10.1002/aenm.201701140

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title = "Antimony (V) Complex Halides: Lead-Free Perovskite-Like Materials for Hybrid Solar Cells",

abstract = "Using bromoantimonate (V) (N-EtPy)[SbBr6] as an example, it is demonstrated that ABX6 compounds can form perovskite-like 3D crystalline frameworks with short interhalide contacts, enabling advanced optoelectronic characteristics of these materials. The designed compound shows an impressive performance in planar junction solar cells delivering external quantum efficiency of ≈80% and power conversion efficiency of ≈4%, thus being comparable with the conventional perovskite material MAPbBr3. The discovery of the first perovskite-like compound ABX6 exhibiting good photovoltaic performance opens wide opportunities for rational design of novel perovskite-like semiconductor materials for advanced electronic and photovoltaic applications.",

keywords = "antimony, halometalates, hybrid solar cells, photovoltaics, ABSORBER, CRYSTAL-STRUCTURE, STABILITY, IODIDE, CATION",

author = "Adonin, {Sergey A.} and Frolova, {Lyubov A.} and Sokolov, {Maxim N.} and Shilov, {Gennady V.} and Korchagin, {Denis V.} and Fedin, {Vladimir P.} and Aldoshin, {Sergey M.} and Stevenson, {Keith J.} and Troshin, {Pavel A.}",

year = "2018",

month = feb,

day = "26",

doi = "10.1002/aenm.201701140",

language = "English",

volume = "8",

journal = "Advanced Energy Materials",

issn = "1614-6832",

publisher = "Wiley-VCH Verlag",

number = "6",

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Antimony (V) Complex Halides : Lead-Free Perovskite-Like Materials for Hybrid Solar Cells. / Adonin, Sergey A.; Frolova, Lyubov A.; Sokolov, Maxim N. и др.

В: Advanced Energy Materials, Том 8, № 6, 1701140, 26.02.2018.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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T1 - Antimony (V) Complex Halides

T2 - Lead-Free Perovskite-Like Materials for Hybrid Solar Cells

AU - Adonin, Sergey A.

AU - Frolova, Lyubov A.

AU - Sokolov, Maxim N.

AU - Shilov, Gennady V.

AU - Korchagin, Denis V.

AU - Fedin, Vladimir P.

AU - Aldoshin, Sergey M.

AU - Stevenson, Keith J.

AU - Troshin, Pavel A.

PY - 2018/2/26

Y1 - 2018/2/26

N2 - Using bromoantimonate (V) (N-EtPy)[SbBr6] as an example, it is demonstrated that ABX6 compounds can form perovskite-like 3D crystalline frameworks with short interhalide contacts, enabling advanced optoelectronic characteristics of these materials. The designed compound shows an impressive performance in planar junction solar cells delivering external quantum efficiency of ≈80% and power conversion efficiency of ≈4%, thus being comparable with the conventional perovskite material MAPbBr3. The discovery of the first perovskite-like compound ABX6 exhibiting good photovoltaic performance opens wide opportunities for rational design of novel perovskite-like semiconductor materials for advanced electronic and photovoltaic applications.

AB - Using bromoantimonate (V) (N-EtPy)[SbBr6] as an example, it is demonstrated that ABX6 compounds can form perovskite-like 3D crystalline frameworks with short interhalide contacts, enabling advanced optoelectronic characteristics of these materials. The designed compound shows an impressive performance in planar junction solar cells delivering external quantum efficiency of ≈80% and power conversion efficiency of ≈4%, thus being comparable with the conventional perovskite material MAPbBr3. The discovery of the first perovskite-like compound ABX6 exhibiting good photovoltaic performance opens wide opportunities for rational design of novel perovskite-like semiconductor materials for advanced electronic and photovoltaic applications.

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KW - halometalates

KW - hybrid solar cells

KW - photovoltaics

KW - ABSORBER

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KW - STABILITY

KW - IODIDE

KW - CATION

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