An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites

V. N. Mitkin; I. P. Asanov; A. K. Sagidullin

doi:10.1134/S0022476618080127

An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites

V. N. Mitkin, I. P. Asanov, A. K. Sagidullin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF_1.2–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF_1+x coated by an outer nanolayer sp²-C–sp³-C–F.

Язык оригинала	английский
Страницы (с-по)	1841-1848
Число страниц	8
Журнал	Journal of Structural Chemistry
Том	59
Номер выпуска	8
DOI	https://doi.org/10.1134/S0022476618080127
Состояние	Опубликовано - 1 дек. 2018

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10.1134/S0022476618080127

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abstract = "The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF1.2–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF1+x coated by an outer nanolayer sp2-C–sp3-C–F.",

keywords = "mesopores, nanocomposites, superstoichiometric fluorocarbon material, texture, thermally expanded graphite, X-ray photoelectron spectroscopy",

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An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites. / Mitkin, V. N.; Asanov, I. P.; Sagidullin, A. K.

В: Journal of Structural Chemistry, Том 59, № 8, 01.12.2018, стр. 1841-1848.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites

AU - Mitkin, V. N.

AU - Asanov, I. P.

AU - Sagidullin, A. K.

PY - 2018/12/1

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N2 - The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF1.2–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF1+x coated by an outer nanolayer sp2-C–sp3-C–F.

AB - The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF1.2–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF1+x coated by an outer nanolayer sp2-C–sp3-C–F.

KW - mesopores

KW - nanocomposites

KW - superstoichiometric fluorocarbon material

KW - texture

KW - thermally expanded graphite

KW - X-ray photoelectron spectroscopy

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