An experimental and numerical study of C4H8O2 esters combustion chemistry

K. N. Osipova; D. A. Knyazkov; I. E. Gerasimov; A. M. Dmitriev; A. G. Shmakov; O. P. Korobeinichev

An experimental and numerical study of C₄H₈O₂ esters combustion chemistry

K. N. Osipova, D. A. Knyazkov, I. E. Gerasimov, A. M. Dmitriev, A. G. Shmakov, O. P. Korobeinichev

Результат исследования: Материалы конференций › материалы › рецензирование

Аннотация

Fatty acids esters are the main biodiesel components. Experimental studies, especially at atmospheric and higher pressures, are of great importance for combustion models development. In this work, we studied near-stoichiometric and rich flames of two isomeric esters - ethyl acetate (EA) and methyl propanoate (MP). We did experiments to study EA/O₂/Ar and MP/O₂/Ar flame structure at atmospheric pressure. For numerical simulation, we used two published mechanisms for esters oxidation. Significant differences between experiment and modeling and between models arise for some intermediates. Analysis of fuels decomposition reaction paths shows MP to decompose mostly in radical reactions. Besides radical reactions, EA undergoes monomolecular decomposition with ethylene and acetic acid formation.

Язык оригинала	английский
Состояние	Опубликовано - 1 янв 2017
Событие	11th Asia-Pacific Conference on Combustion, ASPACC 2017 - Sydney, Австралия Продолжительность: 10 дек 2017 → 14 дек 2017

Конференция

Конференция	11th Asia-Pacific Conference on Combustion, ASPACC 2017
Страна	Австралия
Город	Sydney
Период	10.12.2017 → 14.12.2017

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title = "An experimental and numerical study of C4H8O2 esters combustion chemistry",

abstract = "Fatty acids esters are the main biodiesel components. Experimental studies, especially at atmospheric and higher pressures, are of great importance for combustion models development. In this work, we studied near-stoichiometric and rich flames of two isomeric esters - ethyl acetate (EA) and methyl propanoate (MP). We did experiments to study EA/O2/Ar and MP/O2/Ar flame structure at atmospheric pressure. For numerical simulation, we used two published mechanisms for esters oxidation. Significant differences between experiment and modeling and between models arise for some intermediates. Analysis of fuels decomposition reaction paths shows MP to decompose mostly in radical reactions. Besides radical reactions, EA undergoes monomolecular decomposition with ethylene and acetic acid formation.",

author = "Osipova, {K. N.} and Knyazkov, {D. A.} and Gerasimov, {I. E.} and Dmitriev, {A. M.} and Shmakov, {A. G.} and Korobeinichev, {O. P.}",

year = "2017",

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language = "English",

note = "11th Asia-Pacific Conference on Combustion, ASPACC 2017 ; Conference date: 10-12-2017 Through 14-12-2017",

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An experimental and numerical study of C₄H₈O₂ esters combustion chemistry. / Osipova, K. N.; Knyazkov, D. A.; Gerasimov, I. E.; Dmitriev, A. M.; Shmakov, A. G.; Korobeinichev, O. P.

2017. Документ представлен на 11th Asia-Pacific Conference on Combustion, ASPACC 2017, Sydney, Австралия.

Результат исследования: Материалы конференций › материалы › рецензирование

TY - CONF

T1 - An experimental and numerical study of C4H8O2 esters combustion chemistry

AU - Osipova, K. N.

AU - Knyazkov, D. A.

AU - Gerasimov, I. E.

AU - Dmitriev, A. M.

AU - Shmakov, A. G.

AU - Korobeinichev, O. P.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Fatty acids esters are the main biodiesel components. Experimental studies, especially at atmospheric and higher pressures, are of great importance for combustion models development. In this work, we studied near-stoichiometric and rich flames of two isomeric esters - ethyl acetate (EA) and methyl propanoate (MP). We did experiments to study EA/O2/Ar and MP/O2/Ar flame structure at atmospheric pressure. For numerical simulation, we used two published mechanisms for esters oxidation. Significant differences between experiment and modeling and between models arise for some intermediates. Analysis of fuels decomposition reaction paths shows MP to decompose mostly in radical reactions. Besides radical reactions, EA undergoes monomolecular decomposition with ethylene and acetic acid formation.

AB - Fatty acids esters are the main biodiesel components. Experimental studies, especially at atmospheric and higher pressures, are of great importance for combustion models development. In this work, we studied near-stoichiometric and rich flames of two isomeric esters - ethyl acetate (EA) and methyl propanoate (MP). We did experiments to study EA/O2/Ar and MP/O2/Ar flame structure at atmospheric pressure. For numerical simulation, we used two published mechanisms for esters oxidation. Significant differences between experiment and modeling and between models arise for some intermediates. Analysis of fuels decomposition reaction paths shows MP to decompose mostly in radical reactions. Besides radical reactions, EA undergoes monomolecular decomposition with ethylene and acetic acid formation.

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T2 - 11th Asia-Pacific Conference on Combustion, ASPACC 2017

Y2 - 10 December 2017 through 14 December 2017