An Acid-Catalyzed Cascade Synthesis of Oxaazatetracyclo [5.5.0.03,11.05,9]dodecane Derivatives

Artyom E. Paromov, Sergey V. Sysolyatin, Yuri V. Gatilov

Результат исследования: Научные публикации в периодических изданияхстатья

5 Цитирования (Scopus)

Аннотация

A condensation between mesylamide and glyoxal under highly acidic conditions was studied. A series of new compounds whose structures contain a moiety of oxaazatetracyclo[5.5.0.03,11.05,9]dodecane were synthesized. The synthesis processes were optimized and main factors affecting the assembling of cage products were revealed. Assumptions are made regarding the formation mechanism of these chemical entities. For the first time, compounds have been obtained that include moieties of 2,6,8-trioxa-4,10,12-triazatetracyclo[5.5.0.03,11.05,9]dodecane and 2,4,6-trioxa-8,10,12-triazatetracyclo[5.5.0.03,11.05,9]dodecane. An X-ray diffraction analysis of the new compounds was performed.

Язык оригиналаанглийский
Страницы (с-по)363-373
Число страниц11
ЖурналJournal of Energetic Materials
Том35
Номер выпуска3
DOI
СостояниеОпубликовано - 3 июл 2017

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