Aldose to ketose interconversion: Galactose and arabinose isomerization over heterogeneous catalysts

Dmitry Yu Murzin, Elena V. Murzina, Atte Aho, Mariya A. Kazakova, Alexander G. Selyutin, David Kubicka, Vladimir L. Kuznetsov, Irina L. Simakova

Результат исследования: Научные публикации в периодических изданияхстатья

5 Цитирования (Scopus)

Аннотация

Isomerization of glucose, galactose and arabinose to corresponding keto-sugars was studied in the present work over a range of heterogeneous catalysts. Magnesium aluminates with different ratios between oxides resulting in materials with a Mg/Al ratio from 0.2 to 0.9 were prepared, characterized and evaluated in terms of their catalytic behavior. The catalyst with a Mg/Al ratio close to hydrotalcites was the most efficient considering activity, selectivity and stability. The sugar structure was shown to have a minor influence on catalytic activity and selectivity.

Язык оригиналаанглийский
Страницы (с-по)5321-5331
Число страниц11
ЖурналCatalysis Science and Technology
Том7
Номер выпуска22
DOI
СостояниеОпубликовано - 21 ноя 2017

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Murzin, D. Y., Murzina, E. V., Aho, A., Kazakova, M. A., Selyutin, A. G., Kubicka, D., Kuznetsov, V. L., & Simakova, I. L. (2017). Aldose to ketose interconversion: Galactose and arabinose isomerization over heterogeneous catalysts. Catalysis Science and Technology, 7(22), 5321-5331. https://doi.org/10.1039/c7cy00281e