A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity

Amandine Cadiau, Nikita Kolobov, Sivaranjani Srinivasan, Maarten G. Goesten, Henrik Haspel, Anastasiya V. Bavykina, Mohamed R. Tchalala, Partha Maity, Andrey Goryachev, Artem S. Poryvaev, Mohamed Eddaoudi, Matvey V. Fedin, Omar F. Mohammed, Jorge Gascon

Результат исследования: Научные публикации в периодических изданияхстатья

1 Цитирования (Scopus)

Аннотация

The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.

Язык оригиналаанглийский
Страницы (с-по)13570-13574
Число страниц5
ЖурналAngewandte Chemie
Том132
Номер выпуска32
DOI
СостояниеОпубликовано - 3 авг 2020

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  • Цитировать

    Cadiau, A., Kolobov, N., Srinivasan, S., Goesten, M. G., Haspel, H., Bavykina, A. V., Tchalala, M. R., Maity, P., Goryachev, A., Poryvaev, A. S., Eddaoudi, M., Fedin, M. V., Mohammed, O. F., & Gascon, J. (2020). A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. Angewandte Chemie, 132(32), 13570-13574. https://doi.org/10.1002/ange.202000158