A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity

Amandine Cadiau; Nikita Kolobov; Sivaranjani Srinivasan; Maarten G. Goesten; Henrik Haspel; Anastasiya V. Bavykina; Mohamed R. Tchalala; Partha Maity; Andrey Goryachev; Artem S. Poryvaev; Mohamed Eddaoudi; Matvey V. Fedin; Omar F. Mohammed; Jorge Gascon

doi:10.1002/anie.202000158

A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity

Amandine Cadiau, Nikita Kolobov, Sivaranjani Srinivasan, Maarten G. Goesten, Henrik Haspel, Anastasiya V. Bavykina, Mohamed R. Tchalala, Partha Maity, Andrey Goryachev, Artem S. Poryvaev, Mohamed Eddaoudi, Matvey V. Fedin, Omar F. Mohammed, Jorge Gascon

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

8 Цитирования (Scopus)

Аннотация

The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.

Язык оригинала	английский
Страницы (с-по)	13468-13472
Число страниц	5
Журнал	Angewandte Chemie - International Edition
Том	59
Номер выпуска	32
DOI	https://doi.org/10.1002/anie.202000158
Состояние	Опубликовано - 3 авг 2020

Доступ к документу

10.1002/anie.202000158

Link to publication in Scopus

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Цитировать

Cadiau, A., Kolobov, N., Srinivasan, S., Goesten, M. G., Haspel, H., Bavykina, A. V., Tchalala, M. R., Maity, P., Goryachev, A., Poryvaev, A. S., Eddaoudi, M., Fedin, M. V., Mohammed, O. F., & Gascon, J. (2020). A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. Angewandte Chemie - International Edition, 59(32), 13468-13472. https://doi.org/10.1002/anie.202000158

Cadiau, Amandine ; Kolobov, Nikita ; Srinivasan, Sivaranjani ; Goesten, Maarten G. ; Haspel, Henrik ; Bavykina, Anastasiya V. ; Tchalala, Mohamed R. ; Maity, Partha ; Goryachev, Andrey ; Poryvaev, Artem S. ; Eddaoudi, Mohamed ; Fedin, Matvey V. ; Mohammed, Omar F. ; Gascon, Jorge. / A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. В: Angewandte Chemie - International Edition. 2020 ; Том 59, № 32. стр. 13468-13472.

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title = "A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity",

abstract = "The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.",

keywords = "hydrogen evolution, metal–organic frameworks, photo-oxidation, photocatalysis, titanium, TOPOLOGY, MOF, HYDROGEN-PRODUCTION, CO2 ADSORPTION, LIGAND, EFFICIENT, metal-organic frameworks",

author = "Amandine Cadiau and Nikita Kolobov and Sivaranjani Srinivasan and Goesten, {Maarten G.} and Henrik Haspel and Bavykina, {Anastasiya V.} and Tchalala, {Mohamed R.} and Partha Maity and Andrey Goryachev and Poryvaev, {Artem S.} and Mohamed Eddaoudi and Fedin, {Matvey V.} and Mohammed, {Omar F.} and Jorge Gascon",

note = "{\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2020",

month = aug,

day = "3",

doi = "10.1002/anie.202000158",

language = "English",

volume = "59",

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journal = "Angewandte Chemie - International Edition",

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Cadiau, A, Kolobov, N, Srinivasan, S, Goesten, MG, Haspel, H, Bavykina, AV, Tchalala, MR, Maity, P, Goryachev, A, Poryvaev, AS, Eddaoudi, M, Fedin, MV, Mohammed, OF & Gascon, J 2020, 'A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity', Angewandte Chemie - International Edition, том. 59, № 32, стр. 13468-13472. https://doi.org/10.1002/anie.202000158

A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity. / Cadiau, Amandine; Kolobov, Nikita; Srinivasan, Sivaranjani; Goesten, Maarten G.; Haspel, Henrik; Bavykina, Anastasiya V.; Tchalala, Mohamed R.; Maity, Partha; Goryachev, Andrey; Poryvaev, Artem S.; Eddaoudi, Mohamed; Fedin, Matvey V.; Mohammed, Omar F.; Gascon, Jorge.

В: Angewandte Chemie - International Edition, Том 59, № 32, 03.08.2020, стр. 13468-13472.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity

AU - Cadiau, Amandine

AU - Kolobov, Nikita

AU - Srinivasan, Sivaranjani

AU - Goesten, Maarten G.

AU - Haspel, Henrik

AU - Bavykina, Anastasiya V.

AU - Tchalala, Mohamed R.

AU - Maity, Partha

AU - Goryachev, Andrey

AU - Poryvaev, Artem S.

AU - Eddaoudi, Mohamed

AU - Fedin, Matvey V.

AU - Mohammed, Omar F.

AU - Gascon, Jorge

PY - 2020/8/3

Y1 - 2020/8/3

N2 - The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.

AB - The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.

KW - hydrogen evolution

KW - metal–organic frameworks

KW - photo-oxidation

KW - photocatalysis

KW - titanium

KW - TOPOLOGY

KW - MOF

KW - HYDROGEN-PRODUCTION

KW - CO2 ADSORPTION

KW - LIGAND

KW - EFFICIENT

KW - metal-organic frameworks

UR - http://www.scopus.com/inward/record.url?scp=85085499672&partnerID=8YFLogxK

U2 - 10.1002/anie.202000158

DO - 10.1002/anie.202000158

M3 - Article

C2 - 32315516

AN - SCOPUS:85085499672

VL - 59

SP - 13468

EP - 13472

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 32

ER -