Аннотация
The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.
Язык оригинала | английский |
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Страницы (с-по) | 13468-13472 |
Число страниц | 5 |
Журнал | Angewandte Chemie - International Edition |
Том | 59 |
Номер выпуска | 32 |
DOI | |
Состояние | Опубликовано - 3 авг 2020 |