@article{de8d6d38edc5459eb9f0f78aed6018f6,
title = "A Titanium Metal–Organic Framework with Visible-Light-Responsive Photocatalytic Activity",
abstract = "The one-step synthesis and characterization of a new and robust titanium-based metal–organic framework, ACM-1, is reported. In this structure, which is based on infinite Ti−O chains and 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge-separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.",
keywords = "hydrogen evolution, metal–organic frameworks, photo-oxidation, photocatalysis, titanium, TOPOLOGY, MOF, HYDROGEN-PRODUCTION, CO2 ADSORPTION, LIGAND, EFFICIENT, metal-organic frameworks",
author = "Amandine Cadiau and Nikita Kolobov and Sivaranjani Srinivasan and Goesten, {Maarten G.} and Henrik Haspel and Bavykina, {Anastasiya V.} and Tchalala, {Mohamed R.} and Partha Maity and Andrey Goryachev and Poryvaev, {Artem S.} and Mohamed Eddaoudi and Fedin, {Matvey V.} and Mohammed, {Omar F.} and Jorge Gascon",
note = "We thank the KAUST Office of Sponsored Research for funding through the 2019 CRG program. Matvey V. Fedin thanks the RFBR (18-29-04013). Amandine Cadiau thanks PIA for funding with the grant ANR-18-MOPGA-0009 {"}APPAT{"} and the Occitanie Region. {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2020",
month = aug,
day = "3",
doi = "10.1002/anie.202000158",
language = "English",
volume = "59",
pages = "13468--13472",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "32",
}