A Novel Niobium Cluster Aqua Ion with Capping μ4-Se Ligand

Artem L. Gushchin; Bee Lean Ooi; Pernille Harris; Pavel A. Abramov; Maxim N. Sokolov

doi:10.1002/zaac.201800476

A Novel Niobium Cluster Aqua Ion with Capping μ₄-Se Ligand

Artem L. Gushchin, Bee Lean Ooi, Pernille Harris, Pavel A. Abramov, Maxim N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

The aqueous solution chemistry of niobium is underexplored, and well characterized aqua complexes are scarce. In this contribution, a new niobium aqua complex was obtained by treatment of Zn-reduced ethanolic solution of NbCl₅ with HCl in the presence of a selenide source (ZnSe). This is the first example of selenium containing aqua complex of niobium. The yellow-green aqua complex was isolated by cation-exchange chromatography and transformed into corresponding isothiocyanate complex by ligand exchange, which was crystallized as (PyH)_4.5[H_1.5Nb₄SeO₅(NCS)₁₀]·0.5H₂O. X-ray structural analysis revealed a metal-metal bonded tetranuclear {Nb₄(μ₄-Se)(μ₂-O)₅}⁴⁺ core with a capping μ₄-Se ligand.

Язык оригинала	английский
Страницы (с-по)	398-401
Число страниц	4
Журнал	Zeitschrift fur Anorganische und Allgemeine Chemie
Том	645
Номер выпуска	4
DOI	https://doi.org/10.1002/zaac.201800476
Состояние	Опубликовано - 28 февр. 2019

Доступ к документу

10.1002/zaac.201800476

Другие файлы и ссылки

Link to publication in Scopus

Цитировать

@article{f348cd3758f84bad81201a18117ba28c,

title = "A Novel Niobium Cluster Aqua Ion with Capping μ4-Se Ligand",

abstract = "The aqueous solution chemistry of niobium is underexplored, and well characterized aqua complexes are scarce. In this contribution, a new niobium aqua complex was obtained by treatment of Zn-reduced ethanolic solution of NbCl5 with HCl in the presence of a selenide source (ZnSe). This is the first example of selenium containing aqua complex of niobium. The yellow-green aqua complex was isolated by cation-exchange chromatography and transformed into corresponding isothiocyanate complex by ligand exchange, which was crystallized as (PyH)4.5[H1.5Nb4SeO5(NCS)10]·0.5H2O. X-ray structural analysis revealed a metal-metal bonded tetranuclear {Nb4(μ4-Se)(μ2-O)5}4+ core with a capping μ4-Se ligand.",

keywords = "Crystal structure, High-valent cluster, Niobium, Niobium aqua ion, Selenide bridging ligand, MO, MOLYBDENUM, COMPLEXES, ISOMERISM, DINUCLEAR, CRYSTAL, CHALCOGENIDE CLUSTERS, SE, CHEMISTRY, TRINUCLEAR",

author = "Gushchin, {Artem L.} and Ooi, {Bee Lean} and Pernille Harris and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",

year = "2019",

month = feb,

day = "28",

doi = "10.1002/zaac.201800476",

language = "English",

volume = "645",

pages = "398--401",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "4",

}

A Novel Niobium Cluster Aqua Ion with Capping μ₄-Se Ligand. / Gushchin, Artem L.; Ooi, Bee Lean; Harris, Pernille и др.

В: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 645, № 4, 28.02.2019, стр. 398-401.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - A Novel Niobium Cluster Aqua Ion with Capping μ4-Se Ligand

AU - Gushchin, Artem L.

AU - Ooi, Bee Lean

AU - Harris, Pernille

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

PY - 2019/2/28

Y1 - 2019/2/28

N2 - The aqueous solution chemistry of niobium is underexplored, and well characterized aqua complexes are scarce. In this contribution, a new niobium aqua complex was obtained by treatment of Zn-reduced ethanolic solution of NbCl5 with HCl in the presence of a selenide source (ZnSe). This is the first example of selenium containing aqua complex of niobium. The yellow-green aqua complex was isolated by cation-exchange chromatography and transformed into corresponding isothiocyanate complex by ligand exchange, which was crystallized as (PyH)4.5[H1.5Nb4SeO5(NCS)10]·0.5H2O. X-ray structural analysis revealed a metal-metal bonded tetranuclear {Nb4(μ4-Se)(μ2-O)5}4+ core with a capping μ4-Se ligand.

AB - The aqueous solution chemistry of niobium is underexplored, and well characterized aqua complexes are scarce. In this contribution, a new niobium aqua complex was obtained by treatment of Zn-reduced ethanolic solution of NbCl5 with HCl in the presence of a selenide source (ZnSe). This is the first example of selenium containing aqua complex of niobium. The yellow-green aqua complex was isolated by cation-exchange chromatography and transformed into corresponding isothiocyanate complex by ligand exchange, which was crystallized as (PyH)4.5[H1.5Nb4SeO5(NCS)10]·0.5H2O. X-ray structural analysis revealed a metal-metal bonded tetranuclear {Nb4(μ4-Se)(μ2-O)5}4+ core with a capping μ4-Se ligand.

KW - Crystal structure

KW - High-valent cluster

KW - Niobium

KW - Niobium aqua ion

KW - Selenide bridging ligand

KW - MO

KW - MOLYBDENUM

KW - COMPLEXES

KW - ISOMERISM

KW - DINUCLEAR

KW - CRYSTAL

KW - CHALCOGENIDE CLUSTERS

KW - SE

KW - CHEMISTRY

KW - TRINUCLEAR

UR - http://www.scopus.com/inward/record.url?scp=85060216682&partnerID=8YFLogxK

U2 - 10.1002/zaac.201800476

DO - 10.1002/zaac.201800476

M3 - Article

AN - SCOPUS:85060216682

VL - 645

SP - 398

EP - 401

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 4