A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks

Sergey A. Adonin, Liubov I. Udalova, Pavel A. Abramov, Alexander S. Novikov, Irina V. Yushina, Ilya V. Korolkov, Evgeniy Y. Semitut, Tatiyana A. Derzhavskaya, Keith J. Stevenson, Pavel A. Troshin, Maxim N. Sokolov, Vladimir P. Fedin

Результат исследования: Научные публикации в периодических изданияхстатья

17 Цитирования (Scopus)

Аннотация

In the presence of different cations, reactions of [SbBr6]3− and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix}n− polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6–6.9 kcal mol−1. Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.

Язык оригиналаанглийский
Страницы (с-по)14707-14711
Число страниц5
ЖурналChemistry - A European Journal
Том24
Номер выпуска55
DOI
СостояниеОпубликовано - 1 окт 2018

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