@article{ccb8cfdf4d214f7b9e761969100a5627,
title = "A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks",
abstract = "In the presence of different cations, reactions of [SbBr6]3− and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix}n− polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6–6.9 kcal mol−1. Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.",
keywords = "antimony, DFT calculations, halometalate, photoconductivity, polyhalide, ANIONS, POLYIODIDE NETWORKS, CRYSTAL-STRUCTURE, NONABROMOANTIMONATE(V), COMPOUND, HALOGEN, I-2, IODIDES, BROMINE, CHEMISTRY",
author = "Adonin, {Sergey A.} and Udalova, {Liubov I.} and Abramov, {Pavel A.} and Novikov, {Alexander S.} and Yushina, {Irina V.} and Korolkov, {Ilya V.} and Semitut, {Evgeniy Y.} and Derzhavskaya, {Tatiyana A.} and Stevenson, {Keith J.} and Troshin, {Pavel A.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",
note = "{\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2018",
month = oct,
day = "1",
doi = "10.1002/chem.201802100",
language = "English",
volume = "24",
pages = "14707--14711",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "55",
}