A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks

Sergey A. Adonin; Liubov I. Udalova; Pavel A. Abramov; Alexander S. Novikov; Irina V. Yushina; Ilya V. Korolkov; Evgeniy Y. Semitut; Tatiyana A. Derzhavskaya; Keith J. Stevenson; Pavel A. Troshin; Maxim N. Sokolov; Vladimir P. Fedin

doi:10.1002/chem.201802100

A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks

Sergey A. Adonin, Liubov I. Udalova, Pavel A. Abramov, Alexander S. Novikov, Irina V. Yushina, Ilya V. Korolkov, Evgeniy Y. Semitut, Tatiyana A. Derzhavskaya, Keith J. Stevenson, Pavel A. Troshin, Maxim N. Sokolov, Vladimir P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья

17 Цитирования (Scopus)

Аннотация

In the presence of different cations, reactions of [SbBr₆]³⁻ and I₂ result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {I_x}ⁿ⁻ polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6–6.9 kcal mol⁻¹. Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.

Язык оригинала	английский
Страницы (с-по)	14707-14711
Число страниц	5
Журнал	Chemistry - A European Journal
Том	24
Номер выпуска	55
DOI	https://doi.org/10.1002/chem.201802100
Состояние	Опубликовано - 1 окт 2018

Доступ к документу

10.1002/chem.201802100

Link to publication in Scopus

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Цитировать

Adonin, S. A., Udalova, L. I., Abramov, P. A., Novikov, A. S., Yushina, I. V., Korolkov, I. V., Semitut, E. Y., Derzhavskaya, T. A., Stevenson, K. J., Troshin, P. A., Sokolov, M. N., & Fedin, V. P. (2018). A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks. Chemistry - A European Journal, 24(55), 14707-14711. https://doi.org/10.1002/chem.201802100

Adonin, Sergey A. ; Udalova, Liubov I. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Yushina, Irina V. ; Korolkov, Ilya V. ; Semitut, Evgeniy Y. ; Derzhavskaya, Tatiyana A. ; Stevenson, Keith J. ; Troshin, Pavel A. ; Sokolov, Maxim N. ; Fedin, Vladimir P. / A Novel Family of Polyiodo-Bromoantimonate(III) Complexes : Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks. В: Chemistry - A European Journal. 2018 ; Том 24, № 55. стр. 14707-14711.

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title = "A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks",

abstract = "In the presence of different cations, reactions of [SbBr6]3− and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix}n− polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6–6.9 kcal mol−1. Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.",

keywords = "antimony, DFT calculations, halometalate, photoconductivity, polyhalide, ANIONS, POLYIODIDE NETWORKS, CRYSTAL-STRUCTURE, NONABROMOANTIMONATE(V), COMPOUND, HALOGEN, I-2, IODIDES, BROMINE, CHEMISTRY",

author = "Adonin, {Sergey A.} and Udalova, {Liubov I.} and Abramov, {Pavel A.} and Novikov, {Alexander S.} and Yushina, {Irina V.} and Korolkov, {Ilya V.} and Semitut, {Evgeniy Y.} and Derzhavskaya, {Tatiyana A.} and Stevenson, {Keith J.} and Troshin, {Pavel A.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

note = "{\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2018",

month = oct,

day = "1",

doi = "10.1002/chem.201802100",

language = "English",

volume = "24",

pages = "14707--14711",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "55",

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Adonin, SA, Udalova, LI, Abramov, PA, Novikov, AS, Yushina, IV, Korolkov, IV, Semitut, EY, Derzhavskaya, TA, Stevenson, KJ, Troshin, PA, Sokolov, MN & Fedin, VP 2018, 'A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks', Chemistry - A European Journal, том. 24, № 55, стр. 14707-14711. https://doi.org/10.1002/chem.201802100

A Novel Family of Polyiodo-Bromoantimonate(III) Complexes : Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks. / Adonin, Sergey A.; Udalova, Liubov I.; Abramov, Pavel A.; Novikov, Alexander S.; Yushina, Irina V.; Korolkov, Ilya V.; Semitut, Evgeniy Y.; Derzhavskaya, Tatiyana A.; Stevenson, Keith J.; Troshin, Pavel A.; Sokolov, Maxim N.; Fedin, Vladimir P.

В: Chemistry - A European Journal, Том 24, № 55, 01.10.2018, стр. 14707-14711.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - A Novel Family of Polyiodo-Bromoantimonate(III) Complexes

T2 - Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks

AU - Adonin, Sergey A.

AU - Udalova, Liubov I.

AU - Abramov, Pavel A.

AU - Novikov, Alexander S.

AU - Yushina, Irina V.

AU - Korolkov, Ilya V.

AU - Semitut, Evgeniy Y.

AU - Derzhavskaya, Tatiyana A.

AU - Stevenson, Keith J.

AU - Troshin, Pavel A.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - In the presence of different cations, reactions of [SbBr6]3− and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix}n− polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6–6.9 kcal mol−1. Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.

AB - In the presence of different cations, reactions of [SbBr6]3− and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix}n− polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6–6.9 kcal mol−1. Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.

KW - antimony

KW - DFT calculations

KW - halometalate

KW - photoconductivity

KW - polyhalide

KW - ANIONS

KW - POLYIODIDE NETWORKS

KW - CRYSTAL-STRUCTURE

KW - NONABROMOANTIMONATE(V)

KW - COMPOUND

KW - HALOGEN

KW - I-2

KW - IODIDES

KW - BROMINE

KW - CHEMISTRY

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U2 - 10.1002/chem.201802100

DO - 10.1002/chem.201802100

M3 - Article

C2 - 30020549

AN - SCOPUS:85052955781

VL - 24

SP - 14707

EP - 14711

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

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ER -