A New Synthetic Route to Heteroanthracenes

Vera S. Glukhacheva, Sergey G. Il'yasov, Alexander A. Obraztsov, Yuri V. Gatilov, Ilia V. Eltsov

Результат исследования: Научные публикации в периодических изданияхстатья

1 Цитирования (Scopus)

Аннотация

In this report, we describe the synthesis of 2,3,4a,6,7,8a,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8a,9,9a,10,10a-decahydroanthracene, an octaaza derivative of reduced anthracene, through the reaction of glyoxal bis(nitrosemicarbazone) with glyoxal bis(hydrazone) in aqueous medium at 70 °C as well as by the hydrolytic decomposition of glyoxal bis(nitrosemicarbazone) in aqueous medium at 70 °C in a one-pot transformation. The structure of the resultant compound was confirmed by physicochemical analytical methods and X-ray diffraction. We also obtained the first representative of the cyclic monohydrazone dimer 1,2,4,5,8,9,11,12-octaazacyclotetradeca-5,7,12,14-tetraene-3,10-dione, which exists as lactam and lactim tautomers, through the reaction of glyoxal bis(nitrosemicarbazone) with glyoxal bis(hydrazone) in alkaline aqueous medium.

Язык оригиналаанглийский
Страницы (с-по)1265-1273
Число страниц9
ЖурналEuropean Journal of Organic Chemistry
Том2018
Номер выпуска10
DOI
СостояниеОпубликовано - 14 мар 2018

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