A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect

Andrey Yu Baranov; Mariana I Rakhmanova; Xiuze Hei; Denis G Samsonenko; Dmitri V Stass; Irina Yu Bagryanskaya; Maxim R Ryzhikov; Vladimir P Fedin; Jing Li; Alexander V Artem'ev

doi:10.1039/d3cc00119a

A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect

Andrey Yu Baranov, Mariana I Rakhmanova, Xiuze Hei, Denis G Samsonenko, Dmitri V Stass, Irina Yu Bagryanskaya, Maxim R Ryzhikov, Vladimir P Fedin, Jing Li, Alexander V Artem'ev

Кафедра общей физики ФФ

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

We introduce here a new subclass of copper(I) hybrid emitters simultaneously containing [CuxIy]z- anions and Cu+ cations, separated in space by a Janus head ligand. When UV-irradiated at 298 K, these unique "Two-In-One" hybrids exhibit a short-lived green TADF with near-unity quantum yield and a strong solvatochromic effect. Moreover, they manifest a strong radioluminescence upon X-ray irradiation. These findings open up new possibilities for the design of highly performing TADF materials.

Язык оригинала	английский
Страницы (с-по)	2923-2926
Число страниц	4
Журнал	Chemical communications (Cambridge, England)
Том	59
Номер выпуска	20
Ранняя дата в режиме онлайн	17 февр. 2023
DOI	https://doi.org/10.1039/d3cc00119a
Состояние	Опубликовано - 7 мар. 2023

Предметные области OECD FOS+WOS

2.05 ТЕХНОЛОГИЯ МАТЕРИАЛОВ
2.04 ХИМИЧЕСКИЕ ТЕХНОЛОГИИ
1.04 ХИМИЧЕСКИЕ НАУКИ

Доступ к документу

10.1039/d3cc00119a

Другие файлы и ссылки

https://www.mendeley.com/catalogue/a513d06f-cd67-38e0-9925-eb0a23137a98/

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Baranov, A. Y., Rakhmanova, M. I., Hei, X., Samsonenko, D. G., Stass, D. V., Bagryanskaya, I. Y., Ryzhikov, M. R., Fedin, V. P., Li, J., & Artem'ev, A. V. (2023). A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect. Chemical communications (Cambridge, England), 59(20), 2923-2926. https://doi.org/10.1039/d3cc00119a

@article{974f4f1b3f1f4787b29d61e785e6f9ea,

title = "A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect",

abstract = "We introduce here a new subclass of copper(I) hybrid emitters simultaneously containing [CuxIy]z- anions and Cu+ cations, separated in space by a Janus head ligand. When UV-irradiated at 298 K, these unique {"}Two-In-One{"} hybrids exhibit a short-lived green TADF with near-unity quantum yield and a strong solvatochromic effect. Moreover, they manifest a strong radioluminescence upon X-ray irradiation. These findings open up new possibilities for the design of highly performing TADF materials.",

author = "Baranov, {Andrey Yu} and Rakhmanova, {Mariana I} and Xiuze Hei and Samsonenko, {Denis G} and Stass, {Dmitri V} and Bagryanskaya, {Irina Yu} and Ryzhikov, {Maxim R} and Fedin, {Vladimir P} and Jing Li and Artem'ev, {Alexander V}",

year = "2023",

month = mar,

day = "7",

doi = "10.1039/d3cc00119a",

language = "English",

volume = "59",

pages = "2923--2926",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "20",

}

Baranov, AY, Rakhmanova, MI, Hei, X, Samsonenko, DG , Stass, DV, Bagryanskaya, IY, Ryzhikov, MR, Fedin, VP, Li, J & Artem'ev, AV 2023, 'A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect', Chemical communications (Cambridge, England), том. 59, № 20, стр. 2923-2926. https://doi.org/10.1039/d3cc00119a

A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect. / Baranov, Andrey Yu; Rakhmanova, Mariana I; Hei, Xiuze и др.

В: Chemical communications (Cambridge, England), Том 59, № 20, 07.03.2023, стр. 2923-2926.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect

AU - Baranov, Andrey Yu

AU - Rakhmanova, Mariana I

AU - Hei, Xiuze

AU - Samsonenko, Denis G

AU - Stass, Dmitri V

AU - Bagryanskaya, Irina Yu

AU - Ryzhikov, Maxim R

AU - Fedin, Vladimir P

AU - Li, Jing

AU - Artem'ev, Alexander V

PY - 2023/3/7

Y1 - 2023/3/7

N2 - We introduce here a new subclass of copper(I) hybrid emitters simultaneously containing [CuxIy]z- anions and Cu+ cations, separated in space by a Janus head ligand. When UV-irradiated at 298 K, these unique "Two-In-One" hybrids exhibit a short-lived green TADF with near-unity quantum yield and a strong solvatochromic effect. Moreover, they manifest a strong radioluminescence upon X-ray irradiation. These findings open up new possibilities for the design of highly performing TADF materials.

AB - We introduce here a new subclass of copper(I) hybrid emitters simultaneously containing [CuxIy]z- anions and Cu+ cations, separated in space by a Janus head ligand. When UV-irradiated at 298 K, these unique "Two-In-One" hybrids exhibit a short-lived green TADF with near-unity quantum yield and a strong solvatochromic effect. Moreover, they manifest a strong radioluminescence upon X-ray irradiation. These findings open up new possibilities for the design of highly performing TADF materials.

UR - https://www.mendeley.com/catalogue/a513d06f-cd67-38e0-9925-eb0a23137a98/

U2 - 10.1039/d3cc00119a

DO - 10.1039/d3cc00119a

M3 - Article

C2 - 36799209

VL - 59

SP - 2923

EP - 2926

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 20

ER -