A layered Ag(I)-based coordination polymer showing sky-blue luminescence and antibacterial activity

Maxim I. Rogovoy; Alexey S. Berezin; Yuliya N. Kozlova; Denis G. Samsonenko; Alexander V. Artem'ev

doi:10.1016/j.inoche.2019.107513

A layered Ag(I)-based coordination polymer showing sky-blue luminescence and antibacterial activity

Maxim I. Rogovoy, Alexey S. Berezin, Yuliya N. Kozlova, Denis G. Samsonenko, Alexander V. Artem'ev

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

12 Цитирования (Scopus)

Аннотация

Reaction of 2-methylthiopyrazine (L) with AgClO₄ produces layered coordination polymer (CP), [Ag₂L₂(ClO₄)] _n(ClO₄)_n, in 95% yield. The two-dimensional layers of the latter are assembled from the [Ag₂L₂(ClO₄)] units, in which two metal atoms are bridged by two 2-methylthiopyrazine ligands (μ₂-N,S) and one [ClO₄]⁻ anion to provide short Ag⋯Ag contact of 2.9776(3) Å. At ambient temperature, this CP manifests solid state sky-blue emission consisting of fluorescence and phosphorescence components with the lifetimes of 3.5 ns and 7 ms, respectively. Moreover, the CP being water soluble exhibits antibacterial activity against Staphylococcus aureus.

Язык оригинала	английский
Номер статьи	107513
Число страниц	5
Журнал	Inorganic Chemistry Communications
Том	108
DOI	https://doi.org/10.1016/j.inoche.2019.107513
Состояние	Опубликовано - 1 окт. 2019

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10.1016/j.inoche.2019.107513

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@article{5136a32841f14b36992ce776d6d83bfd,

title = "A layered Ag(I)-based coordination polymer showing sky-blue luminescence and antibacterial activity",

abstract = "Reaction of 2-methylthiopyrazine (L) with AgClO4 produces layered coordination polymer (CP), [Ag2L2(ClO4)] n(ClO4)n, in 95% yield. The two-dimensional layers of the latter are assembled from the [Ag2L2(ClO4)] units, in which two metal atoms are bridged by two 2-methylthiopyrazine ligands (μ2-N,S) and one [ClO4]− anion to provide short Ag⋯Ag contact of 2.9776(3) {\AA}. At ambient temperature, this CP manifests solid state sky-blue emission consisting of fluorescence and phosphorescence components with the lifetimes of 3.5 ns and 7 ms, respectively. Moreover, the CP being water soluble exhibits antibacterial activity against Staphylococcus aureus.",

keywords = "Antibacterial activity, Fluorescence, Layered polymer, Phosphorescence, Pyrazine ligands, Silver(I), ANIONS, AG(I) COMPLEXES, ACID, PHOTOLUMINESCENCE, SILVER(I) COMPLEXES, CRYSTAL-STRUCTURES, PYRAZINE, LIGANDS SYNTHESES, FLUORESCENCE, EMISSION",

author = "Rogovoy, {Maxim I.} and Berezin, {Alexey S.} and Kozlova, {Yuliya N.} and Samsonenko, {Denis G.} and Artem'ev, {Alexander V.}",

year = "2019",

month = oct,

day = "1",

doi = "10.1016/j.inoche.2019.107513",

language = "English",

volume = "108",

journal = "Inorganic Chemistry Communication",

issn = "1387-7003",

publisher = "Elsevier",

}

A layered Ag(I)-based coordination polymer showing sky-blue luminescence and antibacterial activity. / Rogovoy, Maxim I.; Berezin, Alexey S.; Kozlova, Yuliya N. и др.

В: Inorganic Chemistry Communications, Том 108, 107513, 01.10.2019.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - A layered Ag(I)-based coordination polymer showing sky-blue luminescence and antibacterial activity

AU - Rogovoy, Maxim I.

AU - Berezin, Alexey S.

AU - Kozlova, Yuliya N.

AU - Samsonenko, Denis G.

AU - Artem'ev, Alexander V.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - Reaction of 2-methylthiopyrazine (L) with AgClO4 produces layered coordination polymer (CP), [Ag2L2(ClO4)] n(ClO4)n, in 95% yield. The two-dimensional layers of the latter are assembled from the [Ag2L2(ClO4)] units, in which two metal atoms are bridged by two 2-methylthiopyrazine ligands (μ2-N,S) and one [ClO4]− anion to provide short Ag⋯Ag contact of 2.9776(3) Å. At ambient temperature, this CP manifests solid state sky-blue emission consisting of fluorescence and phosphorescence components with the lifetimes of 3.5 ns and 7 ms, respectively. Moreover, the CP being water soluble exhibits antibacterial activity against Staphylococcus aureus.

AB - Reaction of 2-methylthiopyrazine (L) with AgClO4 produces layered coordination polymer (CP), [Ag2L2(ClO4)] n(ClO4)n, in 95% yield. The two-dimensional layers of the latter are assembled from the [Ag2L2(ClO4)] units, in which two metal atoms are bridged by two 2-methylthiopyrazine ligands (μ2-N,S) and one [ClO4]− anion to provide short Ag⋯Ag contact of 2.9776(3) Å. At ambient temperature, this CP manifests solid state sky-blue emission consisting of fluorescence and phosphorescence components with the lifetimes of 3.5 ns and 7 ms, respectively. Moreover, the CP being water soluble exhibits antibacterial activity against Staphylococcus aureus.

KW - Antibacterial activity

KW - Fluorescence

KW - Layered polymer

KW - Phosphorescence

KW - Pyrazine ligands

KW - Silver(I)

KW - ANIONS

KW - AG(I) COMPLEXES

KW - ACID

KW - PHOTOLUMINESCENCE

KW - SILVER(I) COMPLEXES

KW - CRYSTAL-STRUCTURES

KW - PYRAZINE

KW - LIGANDS SYNTHESES

KW - FLUORESCENCE

KW - EMISSION

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DO - 10.1016/j.inoche.2019.107513

M3 - Article

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JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

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