A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

M. S. Zavakhina; D. G. Samsonenko; V. P. Fedin

doi:10.1134/S0022476619020136

A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

M. S. Zavakhina, D. G. Samsonenko, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья

5 Цитирования (Scopus)

Аннотация

The [Cu ₈ (S-mal) ₄ (bptc)(H ₂ O) ₁₂ ] · 0.5H ₄ bptc · 7.5H ₂ O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H ₃ mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H ₄ bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

Язык оригинала	английский
Страницы (с-по)	279-283
Число страниц	5
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	2
DOI	https://doi.org/10.1134/S0022476619020136
Состояние	Опубликовано - 1 фев 2019

Доступ к документу

10.1134/S0022476619020136

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title = "A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid",

abstract = " The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis. ",

keywords = "chiral complexes, coordination polymers, copper(II) complexes, crystal structure, malic acid",

author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

year = "2019",

month = feb,

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doi = "10.1134/S0022476619020136",

language = "English",

volume = "60",

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journal = "Journal of Structural Chemistry",

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A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid. / Zavakhina, M. S.; Samsonenko, D. G.; Fedin, V. P.

В: Journal of Structural Chemistry, Том 60, № 2, 01.02.2019, стр. 279-283.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

AB - The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

KW - chiral complexes

KW - coordination polymers

KW - copper(II) complexes

KW - crystal structure

KW - malic acid

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