A fresh look at the structural diversity of dibenzoylmethanide complexes of lanthanides

Taisiya S. Sukhikh; Dmitry S. Kolybalov; Ekaterina K. Pylova; Denis A. Bashirov; Vladislav Y. Komarov; Natalia V. Kuratieva; Anton I. Smolentsev; Andrew N. Fitch; Sergey N. Konchenko

doi:10.1039/c9nj02059d

A fresh look at the structural diversity of dibenzoylmethanide complexes of lanthanides

Taisiya S. Sukhikh, Dmitry S. Kolybalov, Ekaterina K. Pylova, Denis A. Bashirov, Vladislav Y. Komarov, Natalia V. Kuratieva, Anton I. Smolentsev, Andrew N. Fitch, Sergey N. Konchenko

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

7 Цитирования (Scopus)

Аннотация

An analysis of known synthetic methods for dibenzoylmethanide (dbm^-) complexes of lanthanides of different nuclearity, viz. [Ln(dbm)₃(H₂O)], [Ln₄(dbm)₁₀(OH)₂], [Ln₅(dbm)₁₀(OH)₅] and [KLn(dbm)₄]_n (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb) has been carried out. These methods have been optimized, the range of lanthanides for the compounds extended, and novel complex species, viz. [KLn(Me₂CO)(dbm)₄]₂ (Ln = Eu, Dy, Yb) and [Nd₃(dbm)₈(OH)(H₂O)], have been produced. The nature of the lanthanides in some cases affects the composition of the products formed. The compound [KEu(Me₂CO)(dbm)₄]₂ in solution can transform to [KEu(dbm)₃(OBz)]_n, containing benzoate (OBz^-). For the seven new complexes, the crystal structures have been determined by X-ray diffraction. Photoluminescent properties of the europium complexes have been studied. Their composition and structure influence the emission band shape and quantum yields. Two solid solutions of heterolanthanide complexes [Er_xYb_5-x(dbm)₁₀(OH)₅] (x = 1.2, 2.0) have been prepared, as shown by high-resolution powder XRD analysis.

Язык оригинала	английский
Страницы (с-по)	9934-9942
Число страниц	9
Журнал	New Journal of Chemistry
Том	43
Номер выпуска	25
DOI	https://doi.org/10.1039/c9nj02059d
Состояние	Опубликовано - 7 июл. 2019

Доступ к документу

10.1039/c9nj02059d

Другие файлы и ссылки

Link to publication in Scopus

Fingerprint

Подробные сведения о темах исследования «A fresh look at the structural diversity of dibenzoylmethanide complexes of lanthanides». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

@article{8cf84341187e421eaeac3e171cabfd12,

title = "A fresh look at the structural diversity of dibenzoylmethanide complexes of lanthanides",

abstract = "An analysis of known synthetic methods for dibenzoylmethanide (dbm-) complexes of lanthanides of different nuclearity, viz. [Ln(dbm)3(H2O)], [Ln4(dbm)10(OH)2], [Ln5(dbm)10(OH)5] and [KLn(dbm)4]n (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb) has been carried out. These methods have been optimized, the range of lanthanides for the compounds extended, and novel complex species, viz. [KLn(Me2CO)(dbm)4]2 (Ln = Eu, Dy, Yb) and [Nd3(dbm)8(OH)(H2O)], have been produced. The nature of the lanthanides in some cases affects the composition of the products formed. The compound [KEu(Me2CO)(dbm)4]2 in solution can transform to [KEu(dbm)3(OBz)]n, containing benzoate (OBz-). For the seven new complexes, the crystal structures have been determined by X-ray diffraction. Photoluminescent properties of the europium complexes have been studied. Their composition and structure influence the emission band shape and quantum yields. Two solid solutions of heterolanthanide complexes [ErxYb5-x(dbm)10(OH)5] (x = 1.2, 2.0) have been prepared, as shown by high-resolution powder XRD analysis.",

keywords = "OPTICAL-PROPERTIES, HYDROXO CLUSTERS, LUMINESCENT, TETRANUCLEAR, CRYSTAL, LIGAND, YB, ER",

author = "Sukhikh, {Taisiya S.} and Kolybalov, {Dmitry S.} and Pylova, {Ekaterina K.} and Bashirov, {Denis A.} and Komarov, {Vladislav Y.} and Kuratieva, {Natalia V.} and Smolentsev, {Anton I.} and Fitch, {Andrew N.} and Konchenko, {Sergey N.}",

year = "2019",

month = jul,

day = "7",

doi = "10.1039/c9nj02059d",

language = "English",

volume = "43",

pages = "9934--9942",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "ROYAL SOC CHEMISTRY",

number = "25",

}

A fresh look at the structural diversity of dibenzoylmethanide complexes of lanthanides. / Sukhikh, Taisiya S.; Kolybalov, Dmitry S.; Pylova, Ekaterina K. и др.

В: New Journal of Chemistry, Том 43, № 25, 07.07.2019, стр. 9934-9942.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - A fresh look at the structural diversity of dibenzoylmethanide complexes of lanthanides

AU - Sukhikh, Taisiya S.

AU - Kolybalov, Dmitry S.

AU - Pylova, Ekaterina K.

AU - Bashirov, Denis A.

AU - Komarov, Vladislav Y.

AU - Kuratieva, Natalia V.

AU - Smolentsev, Anton I.

AU - Fitch, Andrew N.

AU - Konchenko, Sergey N.

PY - 2019/7/7

Y1 - 2019/7/7

N2 - An analysis of known synthetic methods for dibenzoylmethanide (dbm-) complexes of lanthanides of different nuclearity, viz. [Ln(dbm)3(H2O)], [Ln4(dbm)10(OH)2], [Ln5(dbm)10(OH)5] and [KLn(dbm)4]n (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb) has been carried out. These methods have been optimized, the range of lanthanides for the compounds extended, and novel complex species, viz. [KLn(Me2CO)(dbm)4]2 (Ln = Eu, Dy, Yb) and [Nd3(dbm)8(OH)(H2O)], have been produced. The nature of the lanthanides in some cases affects the composition of the products formed. The compound [KEu(Me2CO)(dbm)4]2 in solution can transform to [KEu(dbm)3(OBz)]n, containing benzoate (OBz-). For the seven new complexes, the crystal structures have been determined by X-ray diffraction. Photoluminescent properties of the europium complexes have been studied. Their composition and structure influence the emission band shape and quantum yields. Two solid solutions of heterolanthanide complexes [ErxYb5-x(dbm)10(OH)5] (x = 1.2, 2.0) have been prepared, as shown by high-resolution powder XRD analysis.

AB - An analysis of known synthetic methods for dibenzoylmethanide (dbm-) complexes of lanthanides of different nuclearity, viz. [Ln(dbm)3(H2O)], [Ln4(dbm)10(OH)2], [Ln5(dbm)10(OH)5] and [KLn(dbm)4]n (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb) has been carried out. These methods have been optimized, the range of lanthanides for the compounds extended, and novel complex species, viz. [KLn(Me2CO)(dbm)4]2 (Ln = Eu, Dy, Yb) and [Nd3(dbm)8(OH)(H2O)], have been produced. The nature of the lanthanides in some cases affects the composition of the products formed. The compound [KEu(Me2CO)(dbm)4]2 in solution can transform to [KEu(dbm)3(OBz)]n, containing benzoate (OBz-). For the seven new complexes, the crystal structures have been determined by X-ray diffraction. Photoluminescent properties of the europium complexes have been studied. Their composition and structure influence the emission band shape and quantum yields. Two solid solutions of heterolanthanide complexes [ErxYb5-x(dbm)10(OH)5] (x = 1.2, 2.0) have been prepared, as shown by high-resolution powder XRD analysis.

KW - OPTICAL-PROPERTIES

KW - HYDROXO CLUSTERS

KW - LUMINESCENT

KW - TETRANUCLEAR

KW - CRYSTAL

KW - LIGAND

KW - YB

KW - ER

UR - http://www.scopus.com/inward/record.url?scp=85068136191&partnerID=8YFLogxK

U2 - 10.1039/c9nj02059d

DO - 10.1039/c9nj02059d

M3 - Article

AN - SCOPUS:85068136191

VL - 43

SP - 9934

EP - 9942

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 25

ER -