During recent years, the BODIPY core became a popular scaffold for designing photo-removable protecting groups (PPG). In this paper, we report the synthesis of a new mole-cule—8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐boron‐3a,4a‐diaza‐S‐indacene —by the treatment of meso‐(4‐CO2Me‐phenyl)‐BODIPY with excess of MeMgI. The product was characterized by1H,13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG.
Предметные области OECD FOS+WOS
- 1.06 БИОЛОГИЧЕСКИЕ НАУКИ
- 1.04 ХИМИЧЕСКИЕ НАУКИ