TY - JOUR
T1 - 7,7-Difluoropentaphen-6(7H)-one
AU - Dyan, Ok Ton
AU - Zaikin, Pavel A.
N1 - Funding: This research was funded by the Russian Foundation for Basic Research, projects 19-33-60101 and 20-03-00700.
PY - 2022/12/1
Y1 - 2022/12/1
N2 - A new fluorinated pentaphene derivative has been obtained as a potential precursor for fluorinated polycyclic aromatic hydrocarbons. In this work, 7,7-difluoropentaphen-6(7H)-one was prepared from 1,1-difluoroanthracen-2(1H)-one via the Diels–Alder reaction with o-quinodimethane generated in situ from o-bis(dibromomethyl)benzene. The structure of the newly synthesized compound was confirmed by 1H, 13C, 19F NMR, IR and UV/Vis spectroscopy, as well as high-resolution mass spectrometry.
AB - A new fluorinated pentaphene derivative has been obtained as a potential precursor for fluorinated polycyclic aromatic hydrocarbons. In this work, 7,7-difluoropentaphen-6(7H)-one was prepared from 1,1-difluoroanthracen-2(1H)-one via the Diels–Alder reaction with o-quinodimethane generated in situ from o-bis(dibromomethyl)benzene. The structure of the newly synthesized compound was confirmed by 1H, 13C, 19F NMR, IR and UV/Vis spectroscopy, as well as high-resolution mass spectrometry.
KW - Diels–Alder reaction
KW - fluorinated compounds
KW - polycyclic compounds
UR - https://www.scopus.com/inward/record.url?eid=2-s2.0-85144670825&partnerID=40&md5=97b073dcd8f2fb7a9db2d6659c2e6751
UR - https://www.mendeley.com/catalogue/507ba3b2-69b2-3cbe-91a2-432df408b420/
U2 - 10.3390/M1525
DO - 10.3390/M1525
M3 - Article
VL - 2022
JO - MolBank
JF - MolBank
SN - 1422-8599
IS - 4
M1 - M1525
ER -