(1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one

Oleg V. Ardashov; Dina V. Korchagina; Irina Yu Bagryanskaya; Konstantin P. Volcho; Nariman F. Salakhutdinov

doi:10.3390/M1465

(1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one

Oleg V. Ardashov, Dina V. Korchagina, Irina Yu Bagryanskaya, Konstantin P. Volcho, Nariman F. Salakhutdinov

Кафедра органической химии ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

A simple and convenient procedure for the γ, β-dimerization of verbenone was developed. The dimer was obtained during aging with KOH without a solvent. The process proceeds as the formation of the extended enolate of verbenone and its Michael addition to other molecules of verbenone. The product yield was 82% after purification by column chromatography and recrystallization.

Язык оригинала	английский
Номер статьи	M1465
Журнал	MolBank
Том	2022
Номер выпуска	4
DOI	https://doi.org/10.3390/M1465
Состояние	Опубликовано - 1 дек. 2022

Предметные области OECD FOS+WOS

1.06 БИОЛОГИЧЕСКИЕ НАУКИ
1.04 ХИМИЧЕСКИЕ НАУКИ

Доступ к документу

10.3390/M1465

Другие файлы и ссылки

Fingerprint

Подробные сведения о темах исследования «(1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

@article{7fb8a9cc084445818d07b6a5e9e7951e,

title = "(1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one",

abstract = "A simple and convenient procedure for the γ, β-dimerization of verbenone was developed. The dimer was obtained during aging with KOH without a solvent. The process proceeds as the formation of the extended enolate of verbenone and its Michael addition to other molecules of verbenone. The product yield was 82% after purification by column chromatography and recrystallization.",

keywords = "Michael addition, dimerization, extended enolate, verbenone",

author = "Ardashov, {Oleg V.} and Korchagina, {Dina V.} and Bagryanskaya, {Irina Yu} and Volcho, {Konstantin P.} and Salakhutdinov, {Nariman F.}",

note = "Funding: The current work was financially supported by the Russian Foundation for Basic Research (Grant No 19-29-04011).",

year = "2022",

month = dec,

day = "1",

doi = "10.3390/M1465",

language = "English",

volume = "2022",

journal = "MolBank",

issn = "1422-8599",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "4",

}

(1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one. / Ardashov, Oleg V.; Korchagina, Dina V.; Bagryanskaya, Irina Yu и др.

В: MolBank, Том 2022, № 4, M1465, 01.12.2022.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - (1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one

AU - Ardashov, Oleg V.

AU - Korchagina, Dina V.

AU - Bagryanskaya, Irina Yu

AU - Volcho, Konstantin P.

AU - Salakhutdinov, Nariman F.

N1 - Funding: The current work was financially supported by the Russian Foundation for Basic Research (Grant No 19-29-04011).

PY - 2022/12/1

Y1 - 2022/12/1

N2 - A simple and convenient procedure for the γ, β-dimerization of verbenone was developed. The dimer was obtained during aging with KOH without a solvent. The process proceeds as the formation of the extended enolate of verbenone and its Michael addition to other molecules of verbenone. The product yield was 82% after purification by column chromatography and recrystallization.

AB - A simple and convenient procedure for the γ, β-dimerization of verbenone was developed. The dimer was obtained during aging with KOH without a solvent. The process proceeds as the formation of the extended enolate of verbenone and its Michael addition to other molecules of verbenone. The product yield was 82% after purification by column chromatography and recrystallization.

KW - Michael addition

KW - dimerization

KW - extended enolate

KW - verbenone

UR - https://www.scopus.com/inward/record.url?eid=2-s2.0-85144684367&partnerID=40&md5=b499369c17848903e4871d1802a3a5aa

UR - https://www.mendeley.com/catalogue/ae4fa48e-dfd1-33a0-83b0-4d1fe056f2e8/

U2 - 10.3390/M1465

DO - 10.3390/M1465

M3 - Article

VL - 2022

JO - MolBank

JF - MolBank

SN - 1422-8599

IS - 4

M1 - M1465

ER -