Three novel polybromotellurates(IV) were obtained by reactions of TeO2 in conc. HBr with Br2 and tri- or tetraalkylammonium salts. They contain [TeBr6]2– octahedra connected by {Br2} linkers into one- or pseudo-two-dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).

Язык оригиналаанглийский
Страницы (с-по)3264-3269
Число страниц6
ЖурналEuropean Journal of Inorganic Chemistry
Номер выпуска27
СостояниеОпубликовано - 23 июл 2018

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