Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole

D. I. Pavlov; V. V. Poklonova; A. A. Ryadun; D. G. Samsonenko; P. V. Dorovatovskii; V. A. Lazarenko; V. P. Fedin; A. S. Potapov

doi:10.1007/s11172-022-3499-x

Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole

Переведенное название: Синтез и кристаллическая структура люминесцентного металл-органического каркаса на основе 4,7-(4-карбоксифенил)-2,1,3-бензоксадиазола

D. I. Pavlov, V. V. Poklonova, A. A. Ryadun, D. G. Samsonenko, P. V. Dorovatovskii, V. A. Lazarenko, V. P. Fedin, A. S. Potapov

Факультет естественных наук

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

При взаимодействии нитрата цинка(II) с 4,7-(4-карбоксифенил)-2,1,3-бензоксадиазолом и ди(имидазол-1-ил)метаном был синтезирован трехмерный координационный полимер, структура которого была установлена методом рентгеноструктурного анализа. В структуре металл-органического каркаса трехъядерные вторичные строительные блоки связываются между собой в юнинодальную восьмисвязанную сеть с символом {33.418.55.62}, данная топология ранее не встречалась в координационных полимерах. Каркас имеет каналы размерами 7×8 Å2, доступный для растворителя объем составляет 24%. Соединение проявляет эмиссию с максимумом 524 нм при возбуждении 395 нм, квантовый выход фотолюминесценции составляет 19%.

Переведенное название	Синтез и кристаллическая структура люминесцентного металл-органического каркаса на основе 4,7-(4-карбоксифенил)-2,1,3-бензоксадиазола
Язык оригинала	английский
Страницы (с-по)	974-979
Число страниц	6
Журнал	Russian Chemical Bulletin
Том	71
Номер выпуска	5
DOI	https://doi.org/10.1007/s11172-022-3499-x
Состояние	Опубликовано - мая 2022

Предметные области OECD FOS+WOS

1.04 ХИМИЧЕСКИЕ НАУКИ

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@article{b47c7bf660084ce9b15ca1ff3189472a,

title = "Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole",

abstract = "A three-dimensional coordination polymer was synthesized by the reaction of zinc(ii) nitrate with 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole and di(imidazol-1-yl)methane. The crystal structure of the new compound was determined by single-crystal X-ray diffraction. In the structure of the metal-organic framework, the trinuclear secondary building units are connected to each other to form a uninodal eight-connected net with the symbol {33.418.55.62}. This topology has not been previously found in coordination polymers. The framework contains channels with dimensions of 7×8 {\AA}2. The solvent-accessible volume is 24%. The compound exhibits emission with a maximum at 524 nm upon excitation at 395 nm. The photoluminescence quantum yield is 19%.",

keywords = "2,1,3-benzoxadiazole, coordination polymers, di(imidazol-1-yl)-methane, luminescence, metal-organic framework, X-ray diffraction, zinc",

author = "Pavlov, {D. I.} and Poklonova, {V. V.} and Ryadun, {A. A.} and Samsonenko, {D. G.} and Dorovatovskii, {P. V.} and Lazarenko, {V. A.} and Fedin, {V. P.} and Potapov, {A. S.}",

note = "Funding Information: This study was financially supported by the Russian Science Foundation (Project No. 19-73-20087). Physicochemical studies of the synthesized compounds were performed at the Center of Shared Use of the A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, with the financial support from the Ministry of Science and Higher Education of the Russian Federation (Project Nos 121031700321-3 and 121031700313-8). Publisher Copyright: {\textcopyright} 2022, Springer Science+Business Media LLC.",

year = "2022",

month = may,

doi = "10.1007/s11172-022-3499-x",

language = "English",

volume = "71",

pages = "974--979",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "5",

}

Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole. / Pavlov, D. I.; Poklonova, V. V.; Ryadun, A. A.; Samsonenko, D. G.; Dorovatovskii, P. V.; Lazarenko, V. A.; Fedin, V. P.; Potapov, A. S.

В: Russian Chemical Bulletin, Том 71, № 5, 05.2022, стр. 974-979.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole

AU - Pavlov, D. I.

AU - Poklonova, V. V.

AU - Ryadun, A. A.

AU - Samsonenko, D. G.

AU - Dorovatovskii, P. V.

AU - Lazarenko, V. A.

AU - Fedin, V. P.

AU - Potapov, A. S.

N1 - Funding Information: This study was financially supported by the Russian Science Foundation (Project No. 19-73-20087). Physicochemical studies of the synthesized compounds were performed at the Center of Shared Use of the A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, with the financial support from the Ministry of Science and Higher Education of the Russian Federation (Project Nos 121031700321-3 and 121031700313-8). Publisher Copyright: © 2022, Springer Science+Business Media LLC.

PY - 2022/5

Y1 - 2022/5

N2 - A three-dimensional coordination polymer was synthesized by the reaction of zinc(ii) nitrate with 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole and di(imidazol-1-yl)methane. The crystal structure of the new compound was determined by single-crystal X-ray diffraction. In the structure of the metal-organic framework, the trinuclear secondary building units are connected to each other to form a uninodal eight-connected net with the symbol {33.418.55.62}. This topology has not been previously found in coordination polymers. The framework contains channels with dimensions of 7×8 Å2. The solvent-accessible volume is 24%. The compound exhibits emission with a maximum at 524 nm upon excitation at 395 nm. The photoluminescence quantum yield is 19%.

AB - A three-dimensional coordination polymer was synthesized by the reaction of zinc(ii) nitrate with 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole and di(imidazol-1-yl)methane. The crystal structure of the new compound was determined by single-crystal X-ray diffraction. In the structure of the metal-organic framework, the trinuclear secondary building units are connected to each other to form a uninodal eight-connected net with the symbol {33.418.55.62}. This topology has not been previously found in coordination polymers. The framework contains channels with dimensions of 7×8 Å2. The solvent-accessible volume is 24%. The compound exhibits emission with a maximum at 524 nm upon excitation at 395 nm. The photoluminescence quantum yield is 19%.

KW - 2,1,3-benzoxadiazole

KW - coordination polymers

KW - di(imidazol-1-yl)-methane

KW - luminescence

KW - metal-organic framework

KW - X-ray diffraction

KW - zinc

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U2 - 10.1007/s11172-022-3499-x

DO - 10.1007/s11172-022-3499-x

M3 - Article

AN - SCOPUS:85130331375

VL - 71

SP - 974

EP - 979

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

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ER -