Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides

Pavel A. Fedyushin; Larisa Yu Gurskaya; Елена Валерьевна Пантелеева; Борислав Вячеславович Кощеев; Alexander M. Maksimov; Татьяна Валерьевна Рыбалова; Елена Васильевна Зайцева; Евгений Викторович Третьяков

doi:10.17677/fn20714807.2019.02.04

Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides

Переведенное название: Исследование SNF-механизма для получения функционализированных нитронил нитроксидов

Pavel A. Fedyushin, Larisa Yu Gurskaya, Елена Валерьевна Пантелеева, Борислав Вячеславович Кощеев, Alexander M. Maksimov, Татьяна Валерьевна Рыбалова, Елена Васильевна Зайцева, Евгений Викторович Третьяков

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR

Переведенное название	Исследование SNF-механизма для получения функционализированных нитронил нитроксидов
Язык оригинала	английский
Страницы (с-по)	7-8
Число страниц	2
Журнал	FLUORINE NOTES
Том	123
Номер выпуска	2
DOI	https://doi.org/10.17677/fn20714807.2019.02.04
Состояние	Опубликовано - 2019

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Fedyushin, Pavel A. ; Gurskaya, Larisa Yu ; Пантелеева, Елена Валерьевна ; Кощеев, Борислав Вячеславович ; Maksimov, Alexander M. ; Рыбалова, Татьяна Валерьевна ; Зайцева, Елена Васильевна ; Третьяков, Евгений Викторович. / Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides. В: FLUORINE NOTES. 2019 ; Том 123, № 2. стр. 7-8.

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title = "Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides",

abstract = "A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR",

author = "Fedyushin, {Pavel A.} and Gurskaya, {Larisa Yu} and Пантелеева, {Елена Валерьевна} and Кощеев, {Борислав Вячеславович} and Maksimov, {Alexander M.} and Рыбалова, {Татьяна Валерьевна} and Зайцева, {Елена Васильевна} and Третьяков, {Евгений Викторович}",

year = "2019",

doi = "10.17677/fn20714807.2019.02.04",

language = "English",

volume = "123",

pages = "7--8",

journal = "FLUORINE NOTES",

issn = "2071-4807",

number = "2",

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Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides. / Fedyushin, Pavel A.; Gurskaya, Larisa Yu; Пантелеева, Елена Валерьевна; Кощеев, Борислав Вячеславович; Maksimov, Alexander M.; Рыбалова, Татьяна Валерьевна; Зайцева, Елена Васильевна; Третьяков, Евгений Викторович.

В: FLUORINE NOTES, Том 123, № 2, 2019, стр. 7-8.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Exploration of SNF-Approach toward Functionalized Nitronyl Nitroxides

AU - Fedyushin, Pavel A.

AU - Gurskaya, Larisa Yu

AU - Пантелеева, Елена Валерьевна

AU - Кощеев, Борислав Вячеславович

AU - Maksimov, Alexander M.

AU - Рыбалова, Татьяна Валерьевна

AU - Зайцева, Елена Васильевна

AU - Третьяков, Евгений Викторович

PY - 2019

Y1 - 2019

N2 - A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR

AB - A 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium derivative was found to react with perfluoroaromatic compounds with formation of products of fluoro-atom substitution, namely fluorinated aryl(hetaryl)-substituted nitronyl nitroxides. The yields of the fluorinated nitroxides were acceptable in cases of reactions with functionalized perfluorobenzene and perfluoropyridine (25–60%), but was low in case of reaction with perfluorobiphenyl (~ 5%). Molecular and crystal structures of the obtained nitronyl nitroxides were solved by monocrystal X-ray diffraction analysis, and the nature of the radical was ascertained by EPR

U2 - 10.17677/fn20714807.2019.02.04

DO - 10.17677/fn20714807.2019.02.04

M3 - Article

VL - 123

SP - 7

EP - 8

JO - FLUORINE NOTES

JF - FLUORINE NOTES

SN - 2071-4807

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