Yttrium complexes with 3,6-bis(tert-butylcatecholate)

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2 Citations (Scopus)

Abstract

Heterometallic complex [K3Y(Cat36)3(Dme)4] (I) or binuclear complex [Y2(Cat36)3(Dme)3] · Dme (II · Dme) is synthesized, depending on the reactant ratio, by the reaction of YCl3 with 3,6-bis(tertbutylcatecholate) potassium salt (K2Cat36) in 1,2-dimethoxyethane (Dme). Both complexes are characterized by single-crystal X-ray diffraction analysis (CIF files CCDC nos. 1527929 (I) and 1527930 (II)) and 1H and 13C NMR spectroscopy.

Original languageEnglish
Pages (from-to)500-504
Number of pages5
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume43
Issue number8
DOIs
Publication statusPublished - 1 Aug 2017

Keywords

  • quinones
  • rare-earth elements
  • X-ray diffraction analysis
  • yttrium
  • CATECHOLATE
  • GADOLINIUM
  • TRANSITION-METAL-COMPLEXES
  • SEMIQUINONATO COMPLEX
  • FIELD
  • CRYSTAL
  • ELECTRON-TRANSFER
  • LIGANDS
  • CHEMISTRY
  • MAGNETIC-PROPERTIES

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