Y2O2Se as a potential matrix for optical materials: A novel preparation method and optical properties

Maria S. Tarasenko; Alexander S. Kiryakov; Alexey A. Ryadun; Natalia V. Kuratieva; Pavel E. Plyusnin; Nikolay G. Naumov

doi:10.1016/j.mtcomm.2019.100665

Y₂O₂Se as a potential matrix for optical materials: A novel preparation method and optical properties

Maria S. Tarasenko, Alexander S. Kiryakov, Alexey A. Ryadun, Natalia V. Kuratieva, Pavel E. Plyusnin, Nikolay G. Naumov

Research output: Contribution to journal › Article › peer-review

Abstract

A novel one-step method of preparing Y₂O₂Se from Y₂O₃ and Se in a CsCl flux is reported. Pure Y₂O₂Se and Y₂O₂Se:1%RE³⁺ solid solutions were quantitatively prepared and studied. The Y₂O₂Se sample is stable in air up to 680°C and has a melting point of 2015ºC in an inert atmosphere. Optical properties of Y₂O₂Se:1% RE³⁺ samples (RE=Ce – Nd, Sm, Eu, Tb – Yb) were investigated. It was found that Y₂O₂Se:1%RE (RE=Pr, Nd, Sm, Eu, Tb – Yb) are luminescent at room temperature with characteristic emissions of corresponding ions. Ce³⁺ or Eu³⁺ solid solutions are luminescent at 77K and demonstrate quenching at room temperature. The d-f transitions of Ce³⁺ ions in the Y₂O₂Se matrix are slightly shifted to lower energies relative to those in the Y₂O₂S matrix due to the influence of Se^2– in the ligand environment of cerium.

Original language	English
Article number	100665
Number of pages	10
Journal	Materials Today Communications
Volume	21
DOIs	https://doi.org/10.1016/j.mtcomm.2019.100665
Publication status	Published - 1 Dec 2019

Keywords

Luminescence
Rare-Earth elements
Upconversion
Yttrium oxyselenide
LANTHANUM OXYSULFIDE
PR
UP-CONVERSION
CRYSTAL-STRUCTURE
TB
SOLVOTHERMAL SYNTHESIS
EU
LUMINESCENCE
FLUORESCENCE
SELENIDE

OECD FOS+WOS

2.05 MATERIALS ENGINEERING

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10.1016/j.mtcomm.2019.100665

Cite this

@article{0c78f9a0c5234737ab47c29c73e4a493,

title = "Y2O2Se as a potential matrix for optical materials: A novel preparation method and optical properties",

abstract = "A novel one-step method of preparing Y2O2Se from Y2O3 and Se in a CsCl flux is reported. Pure Y2O2Se and Y2O2Se:1%RE3+ solid solutions were quantitatively prepared and studied. The Y2O2Se sample is stable in air up to 680°C and has a melting point of 2015ºC in an inert atmosphere. Optical properties of Y2O2Se:1% RE3+ samples (RE=Ce – Nd, Sm, Eu, Tb – Yb) were investigated. It was found that Y2O2Se:1%RE (RE=Pr, Nd, Sm, Eu, Tb – Yb) are luminescent at room temperature with characteristic emissions of corresponding ions. Ce3+ or Eu3+ solid solutions are luminescent at 77K and demonstrate quenching at room temperature. The d-f transitions of Ce3+ ions in the Y2O2Se matrix are slightly shifted to lower energies relative to those in the Y2O2S matrix due to the influence of Se2– in the ligand environment of cerium.",

keywords = "Luminescence, Rare-Earth elements, Upconversion, Yttrium oxyselenide, LANTHANUM OXYSULFIDE, PR, UP-CONVERSION, CRYSTAL-STRUCTURE, TB, SOLVOTHERMAL SYNTHESIS, EU, LUMINESCENCE, FLUORESCENCE, SELENIDE",

author = "Tarasenko, {Maria S.} and Kiryakov, {Alexander S.} and Ryadun, {Alexey A.} and Kuratieva, {Natalia V.} and Plyusnin, {Pavel E.} and Naumov, {Nikolay G.}",

note = "Funding Information: This work was financially supported by the Ministry of Science and Education of the Russian Federation. Authors thank Irina V. Yushina for recording the diffuse reflection spectrum, Dr. Ruslan E. Nikolaev for melting point measurements (NIIC SB RAS), and Sergey V. Koscheev (Boreskov Institute of Catalysis SB RAS) for XPS measurements. Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",

year = "2019",

month = dec,

day = "1",

doi = "10.1016/j.mtcomm.2019.100665",

language = "English",

volume = "21",

journal = "Materials Today Communications",

issn = "2352-4928",

publisher = "Elsevier",

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TY - JOUR

T1 - Y2O2Se as a potential matrix for optical materials: A novel preparation method and optical properties

AU - Tarasenko, Maria S.

AU - Kiryakov, Alexander S.

AU - Ryadun, Alexey A.

AU - Kuratieva, Natalia V.

AU - Plyusnin, Pavel E.

AU - Naumov, Nikolay G.

N1 - Funding Information: This work was financially supported by the Ministry of Science and Education of the Russian Federation. Authors thank Irina V. Yushina for recording the diffuse reflection spectrum, Dr. Ruslan E. Nikolaev for melting point measurements (NIIC SB RAS), and Sergey V. Koscheev (Boreskov Institute of Catalysis SB RAS) for XPS measurements. Publisher Copyright: © 2019 Elsevier Ltd Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/12/1

Y1 - 2019/12/1

N2 - A novel one-step method of preparing Y2O2Se from Y2O3 and Se in a CsCl flux is reported. Pure Y2O2Se and Y2O2Se:1%RE3+ solid solutions were quantitatively prepared and studied. The Y2O2Se sample is stable in air up to 680°C and has a melting point of 2015ºC in an inert atmosphere. Optical properties of Y2O2Se:1% RE3+ samples (RE=Ce – Nd, Sm, Eu, Tb – Yb) were investigated. It was found that Y2O2Se:1%RE (RE=Pr, Nd, Sm, Eu, Tb – Yb) are luminescent at room temperature with characteristic emissions of corresponding ions. Ce3+ or Eu3+ solid solutions are luminescent at 77K and demonstrate quenching at room temperature. The d-f transitions of Ce3+ ions in the Y2O2Se matrix are slightly shifted to lower energies relative to those in the Y2O2S matrix due to the influence of Se2– in the ligand environment of cerium.

AB - A novel one-step method of preparing Y2O2Se from Y2O3 and Se in a CsCl flux is reported. Pure Y2O2Se and Y2O2Se:1%RE3+ solid solutions were quantitatively prepared and studied. The Y2O2Se sample is stable in air up to 680°C and has a melting point of 2015ºC in an inert atmosphere. Optical properties of Y2O2Se:1% RE3+ samples (RE=Ce – Nd, Sm, Eu, Tb – Yb) were investigated. It was found that Y2O2Se:1%RE (RE=Pr, Nd, Sm, Eu, Tb – Yb) are luminescent at room temperature with characteristic emissions of corresponding ions. Ce3+ or Eu3+ solid solutions are luminescent at 77K and demonstrate quenching at room temperature. The d-f transitions of Ce3+ ions in the Y2O2Se matrix are slightly shifted to lower energies relative to those in the Y2O2S matrix due to the influence of Se2– in the ligand environment of cerium.

KW - Luminescence

KW - Rare-Earth elements

KW - Upconversion

KW - Yttrium oxyselenide

KW - LANTHANUM OXYSULFIDE

KW - PR

KW - UP-CONVERSION

KW - CRYSTAL-STRUCTURE

KW - TB

KW - SOLVOTHERMAL SYNTHESIS

KW - EU

KW - LUMINESCENCE

KW - FLUORESCENCE

KW - SELENIDE

UR - http://www.scopus.com/inward/record.url?scp=85073253591&partnerID=8YFLogxK

U2 - 10.1016/j.mtcomm.2019.100665

DO - 10.1016/j.mtcomm.2019.100665

M3 - Article

AN - SCOPUS:85073253591

VL - 21

JO - Materials Today Communications

JF - Materials Today Communications

SN - 2352-4928

M1 - 100665

ER -