Abstract

Results of X-ray absorption spectroscopy study of Mo-based dispersed catalysts in the coke residue after catalytic steam cracking, catalytic cracking in the absence of water, and hydrocracking processes are reported. It was found that the catalyst precursor (ammonium heptamolybdate) is transformed to three different forms with the different ratios: MoO3, MoO2, and MoS2. After the catalytic steam cracking, the catalyst contains mainly MoO2 (∼74%), whereas after hydrocracking, the prevalent form is MoS2 (∼75%). The precursor after water-free catalytic cracking is transformed into 37% MoO2 and 63% MoS2. The catalyst genesis scheme in the processing of heavy oil was suggested, taking into account that reaction media affect the active phase formation, resulting in different composition and properties of products.

Original languageEnglish
Article number108335
Number of pages4
JournalRadiation Physics and Chemistry
Volume175
Early online date15 May 2019
DOIs
Publication statusPublished - Oct 2020

Keywords

  • Catalytic cracking
  • Catalytic steam cracking
  • EXAFS
  • Heavy oil
  • Hydrocracking
  • Molybdenum oxide
  • Molybdenum sulfide
  • XANES

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