X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes

A. D. Fedorenko, L. N. Mazalov, E. Yu Fursova, V. I. Ovcharenko, A. V. Kalinkin, S. A. Lavrukhina

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1 Citation (Scopus)

Abstract

The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.

Original languageEnglish
Pages (from-to)1166-1172
Number of pages7
JournalJournal of Structural Chemistry
Volume58
Issue number6
DOIs
Publication statusPublished - 1 Nov 2017

Keywords

  • manganese pivalate with isonicotinamide
  • XES
  • XPS

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