Two-Dimensional Coordination Polymer {[Bi(Рyz)I3]}: Structure and Analysis of the Packing Using the Hirshfeld Surface Method

A. N. Usoltsev, S. A. Adonin, A. S. Novikov, M. N. Sokolov, V. P. Fedin

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The reaction of BiI3 with pyrazine in tetrahydrofuran affords the two-dimensional coordination polymer {[Bi(Pyz)I3]} (I), whose structure is determined by X-ray diffraction analysis (СIF file ССDС no. 1904990). The contributions of various interatomic contacts to the crystal packing of compound I are studied using the Hirshfeld surface analysis performed for the elementary unit of compound I. The interatomic distances I···H make the largest contribution to the crystal packing of compound I.

Original languageEnglish
Pages (from-to)23-27
Number of pages5
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume46
Issue number1
DOIs
Publication statusPublished - Jan 2020

Keywords

  • analysis of Hirshfeld surfaces
  • bismuth
  • coordination polymers
  • crystal structure
  • pyrazine
  • M-II
  • CRYSTAL-STRUCTURE
  • COMPLEXES
  • METAL-ORGANIC FRAMEWORK
  • CL
  • NI
  • ARCHITECTURES

Fingerprint

Dive into the research topics of 'Two-Dimensional Coordination Polymer {[Bi(Рyz)I<sub>3</sub>]}: Structure and Analysis of the Packing Using the Hirshfeld Surface Method'. Together they form a unique fingerprint.

Cite this